Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41

Jing Qin; Baoshan Li

doi:10.20944/preprints201612.0094.v1

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preprints.org > chemistry > applied chemistry > doi: 10.20944/preprints201612.0094.v1

Preprint Article Version 1 NOT YET PEER-REVIEWED

Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41

Jing Qin and Baoshan Li ^*

Version 1 : Received: 17 December 2016 / Approved: 18 December 2016 / Online: 18 December 2016 (10:30:52 CET)

How to cite: Qin, J.; Li, B. Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41. Preprints 2016, 2016120094 (doi: 10.20944/preprints201612.0094.v1). Qin, J.; Li, B. Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41. Preprints 2016, 2016120094 (doi: 10.20944/preprints201612.0094.v1).

Cite as:

Qin, J.; Li, B. Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41. Preprints 2016, 2016120094 (doi: 10.20944/preprints201612.0094.v1). Qin, J.; Li, B. Synthesis, Characterization and Catalytic Performance of Well-ordered Crystalline Heteroatom Mesoporous MCM-41. Preprints 2016, 2016120094 (doi: 10.20944/preprints201612.0094.v1).

Abstract

The mesoporous heteroatom molecular sieve MCM-41 bulk crystals with the crystalline phase were synthesized via a one-step hydrothermal method using an ionic complex as template. The ionic complex template was formed by interaction between cetyltrimethylammonium ions and metal complex ion [M (EDTA)]2- (M=Co or Ni ). The materials were characterized by X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy, N2 adsorption–desorption isotherms, and X-ray absorption fine structure spectroscopy. The results showed that the materials possess a highly ordered mesoporous structure with the crystalline phase and possess high uniform ordered arrangement channels. The structure is in the vertical cross directions with a crystalline size of about 12 µm and high specific surface areas. The metal atoms were incorporated into the zeolite frameworks in the form of octahedral coordinate and have a uniform distribution in the materials. The amount of metal complexes formed by metal ion and EDTA is an essential factor for the formation of the vertical cross structure. Comparing to Si-MCM-41, the samples exhibited better conversion, higher selectivity for cumene cracking.

Subject Areas

bulk crystal mesoporous MCM-41; heteroatom molecular sieves; direct hydrothermal method

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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