In the present study, the corrosion resistance of amorphous coating and composite coatings in 3.5 wt.% NaCl, 0.5 M H2SO4 and 10 wt.% NaOH solution were studied. The composite coatings exhibit superior corrosion resistance. When the content of AT13 (Al2O3–13 wt.% TiO2)was 15 wt.%, the composite coating has the lowest corrosion current density (1.75×10-6 A cm-2), which is 5.14×10-5 A cm-2 for Fe-based metallic glassy coating, and the highest corrosion potential (-411 mV), which is -580 mV for Fe-based metallic glassy coating. The breakdown potential of the passivation film in 3.5 wt.% NaCl solution was much higher than that of 316L.The long-time immersion corrosion tests carried out on different coatings showed that the corrosion protection effect of coating was enhanced with the increase of the amount of AT13 added.