Seasonality of Total Columns of CO₂, CH₄, CO, and H₂O Using a COCCON EM27/SUN in the Po Valley

We report the installation and first two years of operation of an EM27/SUN Fourier transform spectrometer at the CNR-ISAC facility in Bologna, Italy, the first instrument of its kind operating in the Po Valley, one of the European region mostly affected by anthropogenic pollution. The instrument is integrated into the COCCON network and it retrieves total columns and column-averaged dry air mole fractions of CO₂, CH₄, CO, and H₂O using the PROFFAST processing chain as per standardized COCCON protocols. The data is filtered with the fitted solar gas shift in the O₂ absorption band for quality controls, and here we study the seasonality of the retrieved products. To assess the relationship between column-integrated and near-surface measurements, we present a case-study comparison against a co-located Cavity Ring-Down Spectroscopy analyzer for CO₂ and CH₄ over a single day, using ceilometer-derived Mixed Aerosol Layer height to interpret the differing diurnal variability between the two techniques, with CRDS showing substantially larger amplitude swings driven by boundary-layer dynamics and surface emission/sink processes. We further validate the EM27/SUN against TROPOMI satellite retrievals of XCH₄ and total-column CO over the full observing period, finding low systematic biases (-0.13% and 0.60% respectively) consistent with satellite mission requirements and comparable to TCCON stations at similar latitudes. As a case-study, we show that both instruments jointly detected an anomalous CO enhancement in July-August 2024 attributable to long-range transport of Canadian wildfires smoke, illustrating the capability of ground-based FTIR observations to identify high-altitude pollution intrusions undetectable by in-situ instrumentation alone. These results establish the EM27/SUN in Bologna as a robust reference for satellite validation and a valuable tool for characterizing atmospheric transport events in the Po Valley.