Smart buildings increasingly depend on dense, distributed sensing infrastructures to improve energy efficiency, indoor environmental quality and operational flexibility. However, large-scale IoT/WSN deployment is still constrained by wiring effort, battery maintenance and limited access to sensing locations. Energy harvesting (EH) offers a promising approach toward low-maintenance and partly autonomous sensing, but its practical value in building automation depends on more than the output of individual transducers. This article presents a structured review of EH for IoT/WSN and edge-enabled building automation, focusing on smart-building, Building Management System (BMS) and Building Automation and Control System (BACS) contexts. Light-based, thermoelectric, mechanical, RF/wireless-power-transfer and hybrid harvesting technologies are interpreted through a system-oriented chain linking energy sources, power management, storage, communication, adaptive operation, gateways, diagnostics and edge intelligence. The synthesis shows that EH is most promising for low-duty-cycle environmental monitoring, envelope and façade sensing, occupancy and human-building interaction, airflow-related sensing, technical monitoring and retrofit automation. The main challenges concern the transition from device autonomy to sensing-service autonomy, complete-node evaluation under real building conditions, interoperability with supervisory systems and diagnostic interpretation of intermittent operation. Further research is also needed on lifecycle value assessment and safe transferability toward mission-critical, military-inspired and closed ecological infrastructure applications.