Organic facies distribution exerts a primary control on hydrocarbon generation potential in clastic-dominated passive margin basins. This study evaluates the spatial and stratigraphic distribution of organic facies and their hydrocarbon potential in the Niger Delta Basin using an extensive organic geochemical dataset. A total of 715 source rock samples from onshore, shallow offshore, and deepwater wells were analyzed using total organic carbon (TOC) and Rock-Eval pyrolysis parameters (S1, S2, S3, HI, OI, Tmax). Organic facies were classified following the Pepper organofacies scheme to assess variations in organic matter type, richness, and generative potential across depositional settings and depobelts. The results show that source rocks of the Akata Formation are dominated by organofacies B and D/E, reflecting mixed marine and terrigenous organic matter with moderate to high hydrogen indices and predominantly oil-prone to mixed oil–gas generative potential. In contrast, source rocks of the Agbada Formation are characterized mainly by organofacies F, dominated by terrestrial organic matter with low hydrogen indices, indicating a gas-prone character. Cretaceous shales beneath the Niger Delta contain mixed organofacies D/E and F and locally exhibit fair to good hydrocarbon potential. TOC values range from 0.1 to 16.9 wt%, with the highest organic richness concentrated within the Akata Formation at depths of approximately 2800–4000 m. Spatial variations in organic facies distribution across depobelts reflect changes in depositional environment, sedimentation rate, and preservation conditions. These results confirm the Akata Formation as the principal effective oil-prone source rock in the Niger Delta Basin and provide important constraints for petroleum system analysis and deepwater exploration risk reduction.