Submitted:
21 June 2026
Posted:
23 June 2026
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Abstract
Keywords:
1. Introduction
- 1.
- a reproducible preprocessing workflow that reconstructs battery sequences and preserves both aggregate and battery-resolved observation structures;
- 2.
- a comparison of sharp, curvature-based, and Bayesian smooth-transition definitions as related but non-equivalent estimands;
- 3.
- a computationally validated hierarchical Bayesian model for battery-specific transition timing and degradation-rate acceleration; and
- 4.
- a controlled comparison of distributed random thinning with trajectory truncation, linking localization stability to the observed post-transition horizon.
2. Battery Technologies, Degradation Mechanisms, and Diagnostic Observability
2.1. Battery Applications and the Value of Degradation Monitoring
| Technology | Application context and principal strengths | Lifecycle limitations | Monitoring relevance |
|---|---|---|---|
| Lead–acid | Backup power, starting, and industrial standby; mature, low initial cost, high surge power, and established recycling | High mass, moderate cycle life, sulfation and corrosion, and maintenance sensitivity | Voltage, current, temperature, charge acceptance, and resistance provide useful ageing information |
| Nickel-based | Industrial equipment and legacy hybrid or portable systems; robust operation and good power capability in selected conditions | Self-discharge, memory effects for NiCd, cadmium toxicity, and lower energy density than Li-ion | Thermal and charging-control history are important for interpreting health |
| Lithium-ion | Electric mobility, portable electronics, and stationary storage; high efficiency, energy and power density, low self-discharge, and broad commercial maturity | Coupled calendar and cycle ageing, thermal sensitivity, cell variability, and safety-management requirements | Strong need for cell-level voltage and temperature supervision and uncertainty-aware SOH estimation |
| Sodium-ion | Emerging stationary and cost-sensitive storage; abundant raw materials and potential cost and sustainability benefits | Lower energy density and less mature field experience; chemistry-dependent cycle life | Monitoring concepts resemble Li-ion but require chemistry-specific calibration and validation |
| Lithium–sulfur | Prospective weight-sensitive applications; high theoretical specific energy and low-cost active sulfur | Polysulfide shuttle, limited cycle life, and lithium-metal-anode challenges | Health indicators must capture rapidly changing electrochemistry and loss mechanisms |
2.2. Ageing Mechanisms and Observable Acceleration
2.3. Operational Observability and the Meaning of
3. Related Work
3.1. Health Indicators and Battery Ageing Knees
3.2. Bayesian and Hierarchical Battery Models
3.3. Incomplete Trajectories and the Contribution of This Study
4. Dataset and Preprocessing
4.1. Data Source, Battery Reconstruction, and Response
4.2. Reversible Cycle Classification
4.3. Aggregate and Battery-Resolved Representations
5. Changepoint Definitions and Aggregate Models
5.1. Notation, Scaling, and Inferential Targets

5.2. Aggregate Deterministic References
5.2.1. No-Transition Linear Model B0
5.2.2. Continuous broken-stick model D1
5.2.3. Smoothing-Spline Curvature Reference S1
5.3. Aggregate Bayesian Smooth-Transition Model A1
6. Hierarchical Bayesian Degradation Model
6.1. Hierarchical Bayesian Smooth-Transition Model H5.1
6.2. Population and Battery-Level Summaries
6.3. Posterior Computation and Diagnostic Gates
7. Model Assessment Under Complete and Incomplete Observations
7.1. Posterior Predictive Assessment
7.2. Sparse-Observation Experiments
7.3. Post-Transition Support and Comparison Limits
8. Results
8.1. Aggregate Transition Estimates

8.2. Hierarchical Transition Timing and Acceleration



8.3. Posterior Predictive Adequacy

8.4. Incomplete Observations and Transition Identifiability
Random thinning.

Trajectory truncation.



9. Discussion
9.1. Battery Interpretation and Heterogeneity
9.2. Applicability to Battery and Energy-Storage Monitoring
9.3. Limitations and Further Work
10. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Symbols
| Charging-to-discharge duration ratio | |
| Aggregate and battery-specific transition midpoint | |
| Aggregate and battery-specific slope increment | |
| w | Smooth-transition width |
| Residual scale | |
| Degrees of freedom of the Student-t distribution | |
| Normal distribution with mean and variance | |
| Half-normal distribution with scale | |
| Uniform distribution on | |
| Exponential distribution with rate | |
| Student-t distribution with degrees of freedom , location , and scale |
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| Mechanism or degradation mode | Possible consequence | Potential observable signatures | Availability in the present dataset |
|---|---|---|---|
| SEI growth and electrolyte side reactions | Loss of cyclable lithium, impedance increase, capacity and power fade | Capacity loss, resistance or EIS change, altered charge acceptance, and heat generation | Only indirect influence through charge/discharge durations and |
| Lithium plating | Loss of lithium, local deposits, accelerated ageing, and potential safety concern | Voltage relaxation, coulombic efficiency, impedance, and temperature response; confirmation often requires dedicated diagnostics | Not directly observed |
| Loss of active material and particle cracking | Reduced electrode utilization, contact loss, and capacity fade | Changes in capacity, incremental-capacity or differential-voltage features, resistance, and mechanical response | Not directly observed |
| Electrolyte oxidation, gas evolution, and interfacial degradation | Increased impedance, pressure, transport limitation, and possible swelling | EIS, pressure or gas sensing, thermal response, and voltage behaviour | Not directly observed |
| Current-collector, tab, or connection degradation | Ohmic loss, voltage drop, non-uniform heating, and local power limitation | DC resistance, pulse response, voltage differences, thermal signals, and vibration diagnostics | Only indirect influence through cycle durations |
| Thermal gradients and operational imbalance | Unequal ageing rates across cells and locally accelerated degradation | Distributed temperature, cell-voltage imbalance, current, and usage history | Temperature and pack context unavailable in the derivative file |
| Quantity | Count | Share | Definition |
|---|---|---|---|
| Source observations | 15,064 | 100.00% | All rows in the distributed file |
| Cycle-index resets | 13 | — | Strict decreases in preserved source order |
| Inferred battery records | 14 | — | One plus the cumulative reset count |
| Candidate long-duration rows | 184 | 1.22% | Either duration s |
| Candidate incomplete rows | 32 | 0.21% | Discharge s or charge s |
| Overlap of candidate flags | 0 | 0.00% | Rows satisfying both candidate rules |
| Regular-eligible rows | 14,848 | 98.57% | Neither candidate flag |
| Complete regular aggregate | 1,121 cycles | — | Median at every represented cycle |
| Retained aggregate | 1,071 cycles | — | At least seven contributing batteries |
| Excluded low-support aggregate | 50 cycles | — | Fewer than seven contributing batteries |
| Code | Observation structure | Model role and estimand | Uncertainty or stability assessment |
|---|---|---|---|
| B0 | 1,071 cycle medians | Constant-slope no-transition reference | No changepoint parameter |
| D1 | 1,071 cycle medians | Sharp breakpoint joining two continuous linear regimes | Moving-block residual bootstrap |
| S1 | 1,071 cycle medians | Interior cycle of maximum smoothing-spline curvature | Smoothing-ladder stability gate |
| A1 | 1,071 cycle medians | Midpoint of an aggregate gradual slope transition | Bayesian posterior interval |
| H5.1 | 14,848 battery–cycle rows | Battery-specific gradual-transition midpoints and draw-wise population summaries | Hierarchical Bayesian posterior intervals and boundary diagnostics |
| Setting or diagnostic | A1 | H5.1 | Acceptance rule |
|---|---|---|---|
| Chains / cores | 4 / 4 | 4 / 4 | — |
| Tuning iterations per chain | 2,000 | 3,000 | — |
| Retained draws per chain | 2,000 | 2,000 | — |
| Random seed | 20260614 | 20260615 | Fixed by configuration |
| Target acceptance | 0.95 | 0.95 | — |
| Maximum tree depth | 10 | 10 | No saturated post-warm-up draws |
| Initialization / metric | auto; PyMC automatic metric | jitter+adapt_full; dense metric | — |
| Maximum rank/default | 1.000 | 1.002229 | |
| Minimum bulk ESS | 1,723 | 4,577.67 | |
| Minimum tail ESS | 2,151 | 4,964.57 | |
| Divergences | 0 | 0 | 0 |
| Tree-depth saturations | 0 | 0 | 0 |
| Minimum E-BFMI | 0.9593 | 0.9394 | |
| Final gate | Passed | Passed | All applicable criteria |
| Model | Transition estimand | Location, cycles | Pre-slope | Post-slope | Status or additional result |
|---|---|---|---|---|---|
| B0 | No transition | — | 0.003810 | 0.003810 | Constant-slope reference |
| D1 | Sharp continuous breakpoint | 576.4 [531.5, 628.8] | 0.002620 | 0.005148 | Slope increment 0.002528 |
| A1 | Smooth-transition midpoint | 503.0 [492.3, 512.9] | 0.001343 | 0.005520 | Width 129.2 [112.7, 146.9] cycles; |
| S1 | Maximum-curvature knee | Not reported | — | — | Smoothing-sensitive; candidate range 263.2 cycles |
| Quantity | Posterior median | 95% HDI |
|---|---|---|
| Population transition midpoint, cycles | 553.872 | [547.128, 560.886] |
| Between-battery midpoint SD, cycles | 141.973 | [130.079, 154.577] |
| Shared transition width, cycles | 183.742 | [172.397, 195.682] |
| Population pre-transition slope | 0.000947 | [0.000829, 0.001058] |
| Population post-transition slope | 0.006516 | [0.006367, 0.006667] |
| Population slope increment | 0.005569 | [0.005327, 0.005829] |
| Shared residual scale, | 0.064493 | [0.063415, 0.065586] |
| A1 aggregate | H5.1 hierarchical | |||||||
|---|---|---|---|---|---|---|---|---|
| Retained |
(cycles) |
90% coverage |
95% coverage |
(cycles) |
Rank |
RMSE |
90% coverage |
95% coverage |
| 90% | 0.162 | 0.331 | 0.486 | 0.693 | 0.280 | 0.352 | ||
| 80% | 0.397 | 0.544 | 0.292 | 0.609 | 0.301 | 0.377 | ||
| 75% | 0.339 | 0.466 | 0.218 | 0.586 | 0.303 | 0.370 | ||
| 70% | 0.039 | 0.058 | 0.081 | 1.191 | 0.249 | 0.309 | ||
| 60% | 0.072 | 0.123 | 0.744 | 0.152 | 0.187 | |||
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