Submitted:
05 July 2024
Posted:
09 July 2024
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Abstract
Keywords:
1. Introduction
2. Materials and Methods
3. Results
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| Sector | No. of SMEs |
Main Characteristics |
Data Collection Methods |
|---|---|---|---|
| Agriculture | 3 | No. of employees: 6-25 Profile: 1 cereal planting, 1 fruit growing, and 1 vegetable growing OSH: 2 had external services and 1 had a designated worker All three were rural |
On-site observations, OSH documents textual content analysis, focus group discussions and chemical risks analysis |
| Research activities in laboratories | 3 | No. of employees: 25-80 OSH: 2 had internal services and 1 had external services All three were urban |
|
| Conservation and restoration laboratory | 3 | No. of employees: 6-25 OSH: 2 had internal services and 1 had external services All three were urban |
| Activity of Participating SMEs | Focus Group no. | Focus Group Code | No. of Participant/Group |
|---|---|---|---|
| Agricultural | 3 | A1, A2, A3 | 4 |
| Research activities in laboratories | 3 | R1, R2, R3 | 3 |
| Conservation and restoration laboratory | 3 | C1, C2, C3 | 3 |
| Component of the Work System | Chemical Risk Factors |
|---|---|
| Production process | Exposure to toxic, caustic, or carcinogenic substances through injection, ingestion, or contact with the skin or eyes can result in harmful effects. |
| Working environment | Inhaling may result in harmful effects when exposed to gasses, vapors, airborne particles of toxic, carcinogenic or caustic aerosols. Airborne flammable substances increase the risk of chemical fires. Explosive atmosphere may be formed when mixing flammable substances with ambient air. |
| Task | Potential risks arising from operations, regulations, incorrect protocols, absence of established procedures, incorrect order of procedures, inadequate personal protective equipment, and improper marking of containers. |
| Workers | Mistakes resulting from mishandling, unsynchronized operations, delays, halts in hazardous locations, neglecting tasks, and failure to use personal protective equipment. Chemical fires can occur due to mishandling and failure to follow safe work practices. |
| Component of the Working System | Chemical Risk Factors |
|---|---|
| Production means | Exposure to hazardous substances used as raw or auxiliary materials through ingestion or, contact with the skin or eyes; possibility of substances being involved in hazardous reactions; possibility of accidents caused by pressurized gasses or hot liquids. |
| Working environment | Gasses and liquid or solid aerosols as well as airborne particles can cause health problems (by inhalation) or by generating fire and explosion accidents. |
| Task | Risks arising from e.g., incorrect, or incomplete OSH protocols, absence of established working procedures. |
| Workers | Risks resulting from mishandling, unsynchronized operations, delays, halts in hazardous locations, neglecting tasks, or not using personal protective equipment (PPE). |

| No. crt. | Description | Controlled (C) | Commonly Controlled (CC) | Occasionally Controlled (OC) | Difficult to Control (DC) | Uncontrolled (UC) | Not Applicable (N/A) |
|---|---|---|---|---|---|---|---|
| 100% | 75%<OC<100% | 25%<UC<75% | 0%<DC<25% | 0% | |||
| 1 | |||||||
| TOTAL | |||||||
| C | CC | OC | DC | UC |
| No. | Compliance Indicator | Definition | |
|---|---|---|---|
| Legal Compliance other than OELS | Compliance of Measured/Estimated Exposure Compared to OELs | ||
| 1. | C—compliant | C=100% | C < 30% of OEL |
| 2. | CC—commonly compliant | 75% ≤ CC < 100 | 30% OEL ≤ CC < 50% OEL |
| 3. | OC—occasionally compliant | 25% ≤ OC < 75 | 50% OEL ≤ OC < 75% OEL |
| 4. | DC—deficient compliance | 0% ≤ DC < 25% | 75% OEL ≤ DC < 100% OEL |
| 5. | UC—uncompliant | UC = 0%. | UC > 50% OEL |
| CF | F |
|---|---|
| FC < 0,15 | 1 |
| 0,15 < FC < 0,50 | 2 |
| FC > 0,50 | 3 |
| Texp (%) | 0-20% | 20%-40% | 40%-60% | 60%-80% | 80%-100% |
|---|---|---|---|---|---|
| Time Class (T) | 1 | 2 | 3 | 4 | 5 |
| Occurrence | Probability Class | Frequency Class x * Exposure Time Class (Fx,T) |
|---|---|---|
| Very rare | 1 | (1,1); (1,2); (2,1) |
| Rare | 2 | (1,3); (1,4); (2,2); (3,1) |
| Uncommon | 3 | (1,5); (2,3); (3,2) |
| Common | 4 | (2,4); (2,5); (3,3) |
| Very common | 5 | (3,4); (3,5) |
| Probability Classes | |||||||
| 1 | 2 | 3 | 4 | 5 | |||
| Very Rare | Rare | Uncommon | Common | Very Common | |||
| Severity Classes | Consequences | (1,1) (1,2) (2,1) | (1,3) (1,4) (2,2) (3,1) | (1,5) (2,3) (3,2) | (2,4) (2,5) (3,3) | (3,4) (3,5) | |
| 5 | Very severe | Death | (5,1) | (5,2) | (5,3) | (5,4) | (5,5) |
| 4 | Severe | Disablement | (4,1) | (4,2) | (4,3) | (4,4) | (4,5) |
| 3 | Large | Medical care and hospitalization for a period of 45-90 days | (3,1) | (3,2) | (3,3) | (3,4) | (3,5) |
| 2 | Medium | Medical care and hospitalization for a period of 3-45 days | (2,1) | (2,2) | (2,3) | (2,4) | (2,5) |
| 1 | Small | Medical care and hospitalization for < 3 days | (1,1) | (1,2) | (1,3) | (1,4) | (1,5) |
| Measured Value (MV) |
MV<30% | 30%≤ MV < 70% | 70%≤ MV < 100% | MV ≥ 100% |
|---|---|---|---|---|
| MV classes | 1 | 2 | 3 | 4 |
| Risk Level | Couple Frequency-*Measured Value Class Chemical Risk (F x Rcm, MV) |
Security Level | ||
|---|---|---|---|---|
| 1 | Small | (1,1) (1,2) | 5 | Maxim |
| 2 | Medium | (1,3) (2,1) (2,2) | 4 | Very large |
| 3 | Large | (3,1) (3,2) | 3 | Large |
| 4 | Very large | (1,4) (2,3) | 2 | Medium |
| 5 | Maxim | (2,4) (3,3) (3,4) | 1 | Small |
| Workplace: | EVALUATION SHEET no. | Working Time: 8 h | ||||||
|---|---|---|---|---|---|---|---|---|
| Nrg = 3 | Nrgr = 2,09 | |||||||
| Risk factor | S | P | NPRL | Recommended Measures | S | P | NPRRL | |
| MEANS OF PRODUCTION | ||||||||
| Working with toxic substances | 2 | 2 | 2 | Workers are not allowed to use toxic substances if they have skin injuries or mucous membrane issues | 2 | 1 | 1 | |
| Working with flammable substances | 3 | 2 | 2 | Toxic or flammable substances that spill on the floor will be neutralized using materials specified by the manufacturer for each substance and will be disposed of at the designated garbage collection site | 3 | 1 | 1 | |
| WORKING ENVIRONMENT | ||||||||
| Vapours, aerosols, dusts—carcinogens: gasses, toxic vapours from varnishes and paints | 4 | 2 | 3 | Ensuring an effective ventilation; Conducting measurements of chemical gases in the workplace | 4 | 1 | 2 | |
| Particulate matter in air, gasses or vapours — explosives: gases, flammable vapors from used substances | 5 | 2 | 3 | Ensuring an efficient ventilation system to eliminate harmful gasses; Proper airing, ventilation, and mandatory gas checks; Providing workers with appropriate PPE | 5 | 1 | 2 | |
| TASK | ||||||||
| Insufficient training | 5 | 2 | 3 | Periodic training of workers on the European systems for classifying and labeling chemical substances | 5 | 1 | 2 | |
| WORKER | ||||||||
| Wrong actions (incorrect handling of containers containing substances) | 5 | 3 | 4 | Storing chemicals in labeled and chemical-resistant containers; Using handling equipment like pumps and valves to minimize direct contact with substances; Providing training on the proper handling of the substances used | 5 | 2 | 3 | |
| Typology | Measures | Actions |
|---|---|---|
| Primary measures | Risk elimination | The measures must directly impact the source of risk factors (intrinsic prevention). |
| Secondary measures | Risk isolation | While risk factors may persist, taking collective protection measures can prevent or reduce their impact on workers. |
| Tertiary measures | Risk avoidance | Organizational measures and regulations on behavior act as barriers to the interaction between risk factors and workers. |
| Quaternary measures | Isolation of the worker | Individual protection can be achieved by wearing personal protective equipment to limit the impact of risk factors. |
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