Preprint Short Note Version 1 Preserved in Portico This version is not peer-reviewed

4-(diphenylphosphoryl)-1-phenylbutane-1,3-dione

Version 1 : Received: 7 December 2023 / Approved: 7 December 2023 / Online: 8 December 2023 (10:20:03 CET)

How to cite: Tatarinov, D.; Bajnazarova, E.; Ali, M.; Dovzhenko, A.; Zairov, R.; Mironov, V.; Mustafina, A. 4-(diphenylphosphoryl)-1-phenylbutane-1,3-dione. Preprints 2023, 2023120553. https://doi.org/10.20944/preprints202312.0553.v1 Tatarinov, D.; Bajnazarova, E.; Ali, M.; Dovzhenko, A.; Zairov, R.; Mironov, V.; Mustafina, A. 4-(diphenylphosphoryl)-1-phenylbutane-1,3-dione. Preprints 2023, 2023120553. https://doi.org/10.20944/preprints202312.0553.v1

Abstract

Novel 4-(diphenylphosphoryl)-1-phenylbutane-1,3-dione was synthesized by the reaction of diketone enamine with diphenylchloro phosphine followed by oxidation and hydrolysis of the enamine phosphine formed. Tautomeric transformation of the diketone moiety of phosphine oxide was investigated by 1H NMR. Three out of five possible tautomers were observed in the 4-(diphenylphosphoryl)-1-phenylbutane-1,3-dione solution. The major tautomer was the form with a diketone fragment.

Keywords

phosphine oxides; ligands; lanthanides; triketones; keto-enolic tautomerism

Subject

Chemistry and Materials Science, Organic Chemistry

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