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A peer-reviewed article of this preprint also exists.
This version is not peer-reviewed
Submitted:
15 November 2023
Posted:
15 November 2023
You are already at the latest version
A peer-reviewed article of this preprint also exists.
This version is not peer-reviewed
Submitted:
15 November 2023
Posted:
15 November 2023
You are already at the latest version
AFS | Atomic fluorescence spectrometry |
APTMS | 3-aminopropyltriethoxysilane |
APDC | Ammonium pyrrolidinedithiocarbamate |
ASA | Arsanilic acid |
BP | 2,2′-bipyridyl |
CBA | Carbarsone |
COF | Covalent organic framework |
CPAA | Charged particle activation analysis |
CRM | Certified reference material |
CVG-AFS | Cold vapour generation-atomic fluorescence spectrometry |
DBT | Dibutyltin |
DDTC | Diethyl dithiocarbamate |
DGT | Diffusive gradients in thin films |
DHBPT | 3,6-bis (3,5-dimethyl-1-H-pyrzol-1-yl)-1,2-dihydro-1,2,4,5-tetrazine |
DMAs | Dimethyl arsenic acid |
DVB | Divinylbenzene |
EDTA | Ethylendiaminetetraacetic acid |
EDXRF | Energy-dispersive X-ray fluorescence |
EGDMA | Ethylene glycol dimethacrylate |
EF | Enrichment factor |
ETAAS | Electrothermal-atomic absorption spectrometry |
FAAS | Flame-atomic absorption spectrometry |
GFAAS | Graphite furnace-atomic absorption spectrometry |
HEMA | Hydroxyethyl methacrylate |
HGAAS | Hydride generation atomic absorption spectrometry |
HG-AFS | Hydride generation atomic fluorescence spectrometry |
8-HQ | 8-hydroxyquinoline |
HPLC | High performance liquid chromatography |
iAs | Inrganic arsenic compounds |
ICP-MS | Inductively coupled plasma mass spectrometry |
ICP-AES | Inductively coupled plasma-atomic emission spectrometry |
ICP-ОES | Inductively coupled plasma-optical emission spectrometry |
IIP | Ion imprinted polymer |
IIP-SPE | Solid phase extraction with ion imprinted polymer |
INAA | Instrumental neutron activation analysis |
ITA | Itaconic acid |
LAICP-MS | Laser ablation inductively coupled plasma mass spectrometry |
LC | Liquid chromatography |
LEP-OES | Liquid electrode plasma-optical emission spectrometry |
LOD | Limit of detection |
LOQ | Limit of quantification |
MAA | Methacrylic acid |
MAC | N-methacryloyl-l-cysteine |
γ-MAPS | Methacryloxypropyltrimethoxysilane |
MBT | Monobutyltin |
MMAs | Monomethyl arsenic acid |
MOF | Metal-organic framework |
NATU | N-allylthiourea |
NOBE | N, O-bismethacryl ethanolamine |
NPA | Nitarsone |
NPs | Nanoparticles |
oAs | Organoarsenic compounds |
PAR | 4-(2-pyridylazo)resorcinol |
PDC | Pyrrolidinedithiocarbamate |
PEG | Poly(ethylene glycol) |
PVA | Poly(vinyl alcohol) |
PVP | Polyvinyl pyrrolidone |
RAFT | Reversible addition-chain fragmentation polymerization |
ROX | Oxarsone |
SA | Sodium alginate |
SBAE | Strong base anion exchange |
SPE | Solid phase extraction |
SPME | Solid phase microextraction |
ST | Styrene |
TAN | 1-(2-thiazolylazo)-2-naphthol |
TBT | Tributyltin |
TLC | Thin layer chromatography |
TMPTMA | Trimethylolpropane trimethacrylate |
1-VIA | 1-vinyl imidazole |
4-VP | 4-vinylphiridine |
Sorbent | Separated species | pH or acidity | Sorption capacity, mg/g |
Sample | Analytical technique | LOD, µg/L |
Ref. |
---|---|---|---|---|---|---|---|
Amberlite IRA 900 | As(III), As(V) |
4.0 | 229.9 | underground hot waters, tap water | ETAAS | - 0.126 |
[22] |
Amberlite IRA 410 | As(III), As(V) |
7–7.5 | 13.2 | natural and drinking waters | spectrofluorometric | - 0.75 |
[25] |
Dowex 1-X8 SAX resin | As(III), As(V) |
6.0-8.0 | Groundwater, waterworks | HR-CS-GFAAS and TXRF | 0.5 | [23] | |
Dowex 1X8 resin | As(III), As(V) |
8 M HCl 8 M acetic acid |
NRCC CRM DORM-2, ground water | INAA | 20–45 | [27] | |
Dowex 1X8 resin | As(III), As(V) |
1 M acetic acid | ground water | CPAA | 10 | [28] | |
717 anion exchange resin | As(III), As(V) |
CRM of riverine water (SLRS-4), lake water |
HG-AFS | 0.02 0.3 |
[26] | ||
tetrahydroborate immobilized on Amberlite IRA-400 | As(III), As(V) |
0.1 M HCl | tap, well, pond and sea waters | FI-HG-AFS | 131 151 |
[29] | |
Lewatit MonoPlus M 500 HY resin |
As(III), As(V) |
7.50 | drinking water | ICP-MS | 0.24 | [31] | |
Lewatit MonoPlus M 500 HY-Fe resin HY-Ag resin |
As(III), As(V), DMAs(V), MMAs(V)V |
9 | drinking, natural and wastewater | ICP-MS or HGAAS |
0.2 | [30] | |
Amberlite IRA 910 | Cr(III), Cr(VI) |
4.5 | seawaters | FI-ICP-MS | 0.03 0.009 |
[32] | |
Lewatit Ionac SR-7 | Cr(III), Cr(VI) |
3 | 17 | Wastewater, tap water | FAAS | - 0.003 |
[33] |
Dowex-1 | Cr(III), Cr(VI) |
4.5 | Soils, sediments | ICP-OES | - 0.02 |
[34] | |
Dowex-1 | Cr(III), Cr(VI) |
4.5 | black tea, green tea, spinach, fruit trees | ICP-OES | 182 212 |
[35] | |
TSK IC-Cation | Cr(III), Cr(VI) |
3.4 | water samples | HPLC-UV-Vis | 0.81 Crtotal 0.61 Cr(VI) |
[39] | |
Dowex 21K and poly 2-(5-methylisoxazol)methacrylamide-co-2- acrylamido-2- methyl-1-propane sulfonic acid-co- divinyl-benzene |
Cr(III), Cr(VI) |
3 | Environmental waters | FAAS | 0.05 0.3 |
[62] | |
Amberlite CG-120 |
Cr(III), Cr(VI) |
spring, drinking and waste waters | FAAS | 0.3 | [40] | ||
Dowex M-41 | Hg(II), methylHg |
3% HCl | Estuarine water samples | FIA-HG-QFAAS | 1.93 0.8 |
[36] | |
Amberlite XAD-7HP |
Sb(III), Sb(V) |
1.5 M HCl | meglumine antimoniate | ICP-OES | 44, 52 |
[37] |
Sorbent | Separated species | pH or acidity | Sorption capacity, mg/g |
Sample | Analytical technique | LOD, µg/L |
Ref. |
---|---|---|---|---|---|---|---|
1,10-Phenanthroline immobilized on Amberlite XAD-16 | Cr(III), Cr(VI) |
5 | 33.2 | industrial waters |
FI-FAAS | 0.09 | [43] |
Xylenol Orange Functionalized Amberlite XAD-16 | Cr(III), Cr(VI) |
5 | 26.7 | industrial waters |
FI-FAAS | 0.11 | [44] |
α-benzoin oxime modified Amberlite XAD-16 | Cr(III), Cr(VI) |
5 | 27.6 | industrial waters |
FI-FAAS | 0.14 | [45] |
Salicylic acid loaded on Amberlite XAD-16 | Cr(III), Cr(VI) |
5 | 29.4 | industrial waters |
FI-FAAS | 0.1 | [46] |
Dithizone modified Dowex Optipore L493 | Cr(III), Cr(VI) |
5 | 31.8 | industrial waters |
FI-FAAS | 0.13 | [47] |
Aminated Amberlite XAD-4 | Cr(III), Cr(VI) |
8 | 67 | Mineral, drinking and waste water | MIS-FAAS | 0.041 | [42] |
Dowex M 4195 chelating resin with bis-picolylamine functional group | Cr(III), Cr(VI) |
2 | 29.7 | tap, river and electroplating water |
FAAS | - 1.94 |
[49] |
Amberlite XAD-1180 resin | Cr(III), Cr(VI) |
0.5 M H2SO4 | food, water, pharmaceutical samples | FAAS | 7.7 Cr(VI) 8.6 Crtotal |
[48] | |
CYPHOS 101 modified Amberlite XAD-1180 | Hg(II), methylHg |
4 M HCl | CRMs (BCR-463 Tuna Fish and Tuna Fish ERM-CE 464); fish samples | ASV |
0.40, 0.50 - |
[51] | |
CYPHOS 101 modified Amberlite XAD-1180 | Hg(II), methylHg |
4 M HCl | CRMs (Tuna Fish ERM-CE 464); fish samples | SW-ASV |
- 0.45 |
[52] | |
CYPHOS 101 modified Amberlite XAD-4, XAD-16 and XAD-1180 | Hg(II), methylHg |
3 M HCl | Water samples | CV-AAS | 2.41 | [67] | |
Aminated Amberlite XAD-4 | Hg(II), methylHg |
4.0 | fish and mussel samples | FI-CVG-AAS | 0.148, 0.157 |
[41] |
Template species |
Functional monomer / cross-linker | Separated species | pH /EF | Capacity, mg/g |
Sample | Analytical technique | LOD, µg/L |
Ref. |
---|---|---|---|---|---|---|---|---|
Chemical immobilization | ||||||||
As(III) | 1-VIA / DVB | As(III), As(V) |
8.5/50 | - | Fish; CRM (dogfish muscle), dog- fish liver, mussel tissue | HPLC-ICP-MS | 0.321 0.391 |
[102] |
As(III) | 1-VIA / DVB | As(III), As(V) |
8/10 | - | Rice | HPLC-ICP-MS | 0.201 0.411 |
[103] |
As(V) | ITA / EGDMA | As(III), As(V) |
3-4/- | - | water | TLC/LA-ICP-MS | - 0.06 |
[106] |
ROX |
NOBE / TMPTMA | ASA, ROX, NPA, CBA |
-/- | 1.708 2.040 1.580 1.504 |
feeds, edible chicken and pork | HPLC | 21.31 41.41 31.71 32.31 |
[104] |
Sn(II) | NATU / EGDMA | Sn(II), Sn(IV) |
6/- | - | Waters, plasma samples | LA-ICP-MS | 0.3, 0.4 |
[107] |
Trapping technique | ||||||||
Sb(III)–APDC complex, | ST / EGDMA | Sb(III), Sb(V) |
5/232 | 6.7 | Waters fruit juices | ETAAS | 3.92 | [108] |
Sb(III) – thionalide complex | MAA / TMPTMA | Sb(III), Sb(V) |
8/25 | - | Surface waters | ICP-OES | 13 | [109] |
Cr(III) – PDC complex | AA / EGDMA | Cr(III), Cr(VI) |
3.50–4.75/10 | 1.34 | tap and river water, municipal sewage | ETAAS | 0.018 | [112] |
Cr(III)– 8-HQ | ST / DVB | Cr(III), Cr(VI) |
9/33 | 8.5 | CRM of waste water | FAAS | 2.1 | [111] |
Cr(III) – nicotinate complex | AA / EGDMA | Cr(III), Cr(VI) |
9–10/- | - | wastewater | FAAS | 0.08 | [112] |
Cr(III)– 1,10-phenanthroline complex | ST or ST+4-VP / EGDMA | Cr(III), Cr(VI) |
4.5/20 | 1.186 | tap water and infusion of a green tea | ETAAS | 0.018 | [113] |
Fe(II) – BP complex | 4-VP / TMPTMA | Fe(II), Fe(III) |
7/- | 28.017 | wine | ETAAS | 0.03 Fetotal, 0.1 Fe(III) |
[114] |
Fe(II) – BP or PAR complex | 4-VP or HEMA / TMPTMA | Fe(II), Fe(III) |
7/- | 1.797 | Surface waters | ETAAS | 0.5, 0.2 |
[115] |
Fe(III) – DHBPT complex | MAA / EGDMA | Fe(II), Fe(III) |
4.5/- | 40.41 | Foods, waters | FAAS | - 1.56 Fe(III) |
[116] |
Fe(III) – 8-HQ complex | MAA / DVB | Fe(II), Fe(III) |
2.5/240 | 1707 | drinking water | FAAS | - | [117] |
Hg(II) –TAN complex | MAA / TMPTMA | Hg(II), methylHg |
7/− | 32.07 | seawater, mineral waters | CV-AAS | 0.006 |
[118] |
Hg(II) – PDC complex | MAA / TMPTMA | 7/25 | 64.07 | river water | CV-AAS | 0.0153, 0.023 |
[119] | |
Hg(II) – TAN complex | MAA or VIA or HEMA / TMPTMA | Hg(II), methylHg |
7/− | 73.77 (MAA), 78.07 (VIA) | surface waters | CV-AAS | 0.005, 0.006 |
|
MeHg- phenobarbital complex | MAA / EGDMA | Hg(II), methylHg, ethylHg |
8/50 | - | seawater | HPLC-ICP-MS | 0.003, 0.002, 0.002 |
[121] |
MeHg- phenobarbital complex | MAA / EGDMA | methylHg, Hg(II) |
9/50 | - | seaweed | LC-ICP-MS | 0.0071 0.021 |
[122] |
Sn(IV) – PAR complex | MAA / EGDMA | Sn(IV), Sn(II) |
8/- | tap water, river water, food samples |
GF-AAS | 1.3 | [123] | |
Surface imprinting technique | ||||||||
As(III)–MAC complex As(V)–MAC complex |
HEMA / EGDMA on Fe3O4 HEMA / EGDMA on Fe3O4 |
As(III), As(V) |
5/- | 76.83 85.57 |
water | ICP-MS | - | [131] |
Cr(III) | 3-aminopropyl-triethoxysilane on SBA-15 | Cr(III), Cr(VI) |
6/− | 38.50 | plating and leather wastewater | ICP-AES and UV-vis | 0.53 |
[128] |
Cr(VI) | 1-(trimethoxysilylpro-pyl)-3-methylimid-azolium on silica gel | Cr(III), Cr(VI) |
2–3/- |
6.427 |
Surface waters | ETAAS | - 0.02 |
[137] |
Cr(VI) | 1-(trimethoxysilyl-propyl)-3-methyl-imidazolium on µSiO2 | Cr(III), Cr(VI) |
3/- |
9.47 |
textiles | ETAAS | - 0.0156 |
[126] |
Cr(VI) | MAA and 4-VP / MPTMS on SBA-15 | Cr(III), Cr(VI) |
2/- |
96.32 |
water | ICP-AES | - | [129] |
Cr(VI) | VIA, APTMS / MPTMS on Fe3O4 | Cr(III), Cr(VI) |
3/98 |
2.49 |
water | FAAS | - 0.29 |
[132] |
Hg(II) – PDC complex | MAA / TMPTMA on silica gel | Hg(II), methylHg |
7/− | wine | CV-AAS. | 0.02 | [138] | |
Hg(II) – dithizone complex | 3-aminopropyltriethoxy-silane | Hg(II), methylHg |
6/− | human hair, fish meat, seawater | AFS | 0.015 0.02 |
[139] | |
MeHg-PDC complex | MAA / TMPTMA on Fe3O4@SiO2 |
methylHg, ethylHg, Hg(II) |
5/25 | 25 | Natural water |
CE-ICP-MS | 0.0842 | [133] |
MOF / Modification | Chemical species | Sample | EF | Analytical technique | LOD, ng/L |
Ref. |
---|---|---|---|---|---|---|
MIL-101(Fe) / dithiocarbamate-modified magnetite nanoparticles | Cr(VI) | Water, tea | 470 | ETAAS | 1 | [148] |
MIL-101(Cr) / amino dithiocarbamate modified magnetite nanoparticles | Se(IV) | Waters | 220 | ETAAS | 10 |
[149] |
MIL-101(Cr)/1-(2-pyridylazo)-2-naphthol-modified magnetite nanoparticles | Sn(IV) | Waters | 400 | ETAAS | 5 | [150] |
MIL-101(Fe) / morin-modified magnetite nanoparticles | V(V) | Waters | 400 | ETAAS | 3 | [151] |
MIL-101(Cr) / aminodibenzo-18-crown-6 magnetite nanoparticles | Tl(I) | Waters | 857 | ETAAS | 1.5 | [152] |
MOF-199 / dithiocarbamate modified magnetite nanoparticles | As(III) | Waters | 240 | ETAAS | 1.2 | [153] |
MIL-101(Fe) mixed-matrix membrane | As(V) | Waters | - | EDXRF | 0.0941 | [154] |
UiO-66 [Zr6O4(OH)4(bdc)6] UiO-66 / cysteine-modified |
Hg2+ phenylHg+ methylHg+ |
Waters | - | TR-ETAAS | 0.061 0.061 0.061 |
[156] |
Magnetic Zr-terephtalate MOF composite Magnetic Zr-terephtalate MOF composite / mercapto-functionalized |
As(V) MMA DMA As(III) |
Squamous carcinoma cells | 23 25 24 24 |
Online MSPME-ICP-MS | 4.8 3.8 6.3 7.1 |
[157] |
UiO-66-SH / magnetite nanoparticles | Hg2+ methylHg+ |
Waters, fish | 45.7 47.6 |
MSPE-HPLC-ICP-MS | 1.4 2.6 |
[158] |
Material / Modification | Chemical species | Sample | Analytical technique | LOD, ng/L |
Ref. |
---|---|---|---|---|---|
Chitosan grafted with 2-hydroxyethyltrimethyl ammonium chloride | Cr(VI) | Pond, lake, tap water | FAAS | 20 | [166] |
Chitosan modified magnetic nanoparticles cross-linked with AgNPs | Cr(III) Total Cr |
Environmental waters | ICP-OES | 0.021 0.031 |
[167] |
Chitosan film / loaded with silver nanoparticles | Cr(VI) Cr(III) |
Surface waters | ICP-MS | 0.022 | [168] |
Chitin, Chitosan-immobilized sodium silicate | As(V) | Waters | HGAAS ICP-MS |
- | [169] |
Diethylene Triamine Cross-Linked Chitosan | Se(VI) | Environmental waters | ICP-OES | 12 | [170] |
Chitosan based chelating resin / modified with 3,4,5-trihydroxy benzoic acid | Cr(VI) Cr(III) |
- | ICP-AES | - | [171] |
Magnetic chitosan microspheres | PVP-AgNPs Cit-AgNPs PVA-AgNPs |
Environmental water, waste water | ICP-MS | 0.0232 0.0162 0.0212 |
[172] |
Cellulose fibers / modified with L-cysteine | Hg(II) MeHg |
Waters Cosmetics |
CVG-AFS |
1 3 |
[173] |
Cellulose / dithiocarbamate-modified | Se(IV) Total Se |
Wastewater |
LEP-OES | [174] | |
Cellulose membranes / coated with amorphous silica / amino-silanized | Cr(VI) | Waters | EDXRF | 0.161 | [175] |
Cellulose membranes / grafted with TiO2 | Se(IV) As(V) |
Waters | EDXRF | 0.41 0.251 |
[176] |
Carboxymethyl cellulose nanolayer / cross-linked using glutaraldehyde onto surface of nano-ZrO2 | Cr(VI) Cr(III) |
Tap and sea water, industrial wastewater | AAS | - | [177] |
Cellulose fabric / modified with a sol-gel/polytetrahydrofuran composite | Cr(III) Cr(VI) |
Ground water Drinking water Waste water |
HPLC-UV | 0.0011 0.0031 |
[178] |
Microcrystalline cellulose | Cr(III) | Tap and bottled waters | ETAAS | 6 | [179] |
Cellulose membrane / coated with silica / modified with (3-mercaptopropyl)-trimethoxysilane | As(III) | Tap, sea, ground and waste water | EDXRF | 0.0451 | [180] |
β-cyclodextrin / modified with ionic liquid / attached on Fe3O4 nanoparticles | Mn(II) Mn(VII) |
Tap, lake and mineral water | ICP-OES | 0.152 0.272 |
[181] |
β-cyclodextrin cross-linked polymer | Cr(III) | Tap water | GFAAS | 0.0562 | [182] |
Magnetic dextran (Sephadex G-150) |
Cr(VI) Total Cr |
Mineral water, Tea, Coffee |
Voltammetry | 0.013 | [183] |
Poly(vinyl alcohol)/sodium alginate/AuNPs hydrogel membranes | Cr(III) Cr(VI) |
Waters | ETAAS | 0.0012 0.012 |
[187] |
Immobilized Cr(III) Binding Phages | Cr(III) | Water | ICP-MS | 15 | [184] |
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