Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Hydrolysis Optimization of by-Products from the Potato Processing Industry and Biomethane Production from Starch Hydrolysates

Version 1 : Received: 22 September 2023 / Approved: 25 September 2023 / Online: 26 September 2023 (04:39:11 CEST)

A peer-reviewed article of this Preprint also exists.

Theodosi Palimeri, D.; Papadopoulou, K.; Vlyssides, A.G.; Vlysidis, A.A. Hydrolysis Optimization of By-Products from the Potato Processing Industry and Biomethane Production from Starch Hydrolysates. Sustainability 2023, 15, 14860. Theodosi Palimeri, D.; Papadopoulou, K.; Vlyssides, A.G.; Vlysidis, A.A. Hydrolysis Optimization of By-Products from the Potato Processing Industry and Biomethane Production from Starch Hydrolysates. Sustainability 2023, 15, 14860.

Abstract

The aim of this study is to examine an efficient and environmental friendly process for hydrolyzing starch, an industrial-derived by-product of the potato processing industry, and to use the produced hydrolysates as substrates for methane production. A full factorial experiment was designed and the optimal concentrations of FeSO4·7H2O, H2O2 and temperature were determined obtaining a yield of 99.5%, with a total carbohydrates content equal to 28.65 g, when the input parameters were at their high level: FeSO4·7H2O 1.00g/L, H2O2 0.51 g/L and temperature 70.0oC. The hydrolysis kinetics were also examined revealing that temperature was the most important factor among the three optimization parameters. Furthermore, biodegradability tests were carried out to measure the methane production potential from the produced hydrolysates. The specific methanogenic activity was reached 0.669 g CODCH4/gVSS-day proving the effectiveness of the hydrolysis process and highlighting the potential of this food manufacturing by-product for bioenergy production. A preliminary cost analysis showed that a small investment for utilizing the starch in an existing wastewater treatment facility of a potato processing industry becomes profitable before the end of the 3rd year obtaining a NPV 37.5% higher than the NPV of the current utilization scenario.

Keywords

Starch hydrolysis; waste valorization; biomethane production; anaerobic digestion; potato processing industry; Fenton reagents

Subject

Environmental and Earth Sciences, Waste Management and Disposal

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