Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Study of the Efficiency of Layered Double Hydroxide-based Corrosion Inhibitors on Mild Steel in Chemical Pickling in HCl Medium

Version 1 : Received: 14 June 2023 / Approved: 16 June 2023 / Online: 16 June 2023 (05:40:46 CEST)

How to cite: Salim, A.; Elharrari, S.; Guilbert, G.; Lahem, D.; Semane, A.; Harrad, M.A.; Badreddine, M.; Legrouri, A.; Takky, D.; Naimi, Y. Study of the Efficiency of Layered Double Hydroxide-based Corrosion Inhibitors on Mild Steel in Chemical Pickling in HCl Medium. Preprints 2023, 2023061177. https://doi.org/10.20944/preprints202306.1177.v1 Salim, A.; Elharrari, S.; Guilbert, G.; Lahem, D.; Semane, A.; Harrad, M.A.; Badreddine, M.; Legrouri, A.; Takky, D.; Naimi, Y. Study of the Efficiency of Layered Double Hydroxide-based Corrosion Inhibitors on Mild Steel in Chemical Pickling in HCl Medium. Preprints 2023, 2023061177. https://doi.org/10.20944/preprints202306.1177.v1

Abstract

The materials used as corrosion inhibitors are [Zn-Al-Cl], [Mg-Al-Cl], [Ni-Fe-Cl], and [Co-Fe-Cl] layered double hydroxides (LDHs). They were synthesized by coprecipitation and characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), and thermal anal-yses. The efficiency of these corrosion inhibitors on mild steel in concentrated hydrochloric acid (18.5%) at 60°C (chemical pickling conditions of steel) was studied using electrochemical and gravimetric methods for different concentrations. The surface morphology and composition were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. The inhibitory efficiency in the case of 1.2 g.L-1 LDH was found to be 83.33%, 83.65%, 68.38%, and 74.73% for [Ni- Fe-Cl], [Zn-Al-Cl], [Co-Fe-Cl], and [Mg-Al-Cl], respectively.

Keywords

layered double hydroxides; corrosion inhibitor; hydrochloric acid; chemical pickling; mild steel

Subject

Chemistry and Materials Science, Electrochemistry

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