Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

A Deep Neural Network Regression of the Cahn–Hilliard Single-Particle Thermal Model for LiFePO4 Batteries

Version 1 : Received: 4 June 2023 / Approved: 5 June 2023 / Online: 5 June 2023 (09:01:49 CEST)

How to cite: Painter, R.; Parthasarathy, R.; Li, L.; Embry, I.; Sharpe, L.; Hargrove, S.K. A Deep Neural Network Regression of the Cahn–Hilliard Single-Particle Thermal Model for LiFePO4 Batteries. Preprints 2023, 2023060283. https://doi.org/10.20944/preprints202306.0283.v1 Painter, R.; Parthasarathy, R.; Li, L.; Embry, I.; Sharpe, L.; Hargrove, S.K. A Deep Neural Network Regression of the Cahn–Hilliard Single-Particle Thermal Model for LiFePO4 Batteries. Preprints 2023, 2023060283. https://doi.org/10.20944/preprints202306.0283.v1

Abstract

Lithium-ion batteries serve as the primary sources of power for electric vehicles (EVs) and hybrid electric vehicles (HEVs). For vehicle applications, battery management systems (BMSs) are nec-essary to protect lithium-ion batteries from overheating and to ensure optimum vehicle perfor-mance. Our approach to developing a BMS was based on recent advances in the application of phase field models for lithium-ion batteries. In particular, our reduced-order model (ROM) uti-lized a dataset generated from the COMSOL® Multiphysics simulation of the Cahn–Hilliard equation for a single particle of a lithium iron phosphate (LiFePO4) cathode: an example of using a reduced-order model (ROM) based on a single-particle model (SPM). The main innovation of our ROM is that the SPM is fully coupled to a heat transfer model at the battery cell level. We utilized principal component analysis to identify a lower-order model that could reproduce the battery’s voltage and temperature response for ambient temperatures ranging from 253 to 298 K and for discharge rates ranging from 1 C to 20.5 C. The reduced-order dataset was then fitted to the ex-perimental data for an A123 Systems 26650 2.3 Ah cylindrical battery using deep neural network (DNN) regression.

Keywords

lithium-ion batteries; LIB; LiFePO4; electric vehicles; Cahn–Hilliard; principal component analysis; neural networks

Subject

Engineering, Chemical Engineering

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