Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

New Catalysts Based on Carboxylate Sn(IV) Complexes Used in the Oxidation Reaction of 3,5-Di-Tert-Butylcatechol to 3,5- Di-Tert-Butyl-O-Benzoquinone

Abderrahim Titi
,
Mohamed Dahmani
,
Abdullah Y. A. Alzahrani
ORCID logo ,
Mohamed El Kodadi
,
Mohammed Ettouhami
* ,
Abderrahmane Yahyi
,
El Bekkaye Yousfi
,
Rachid Touzani
* ORCID logo
Version 1 : Received: 26 April 2023 / Approved: 26 April 2023 / Online: 26 April 2023 (11:09:52 CEST)

A peer-reviewed article of this Preprint also exists.

Titi, A.; Dahmani, M.; Abbaoui, Z.; El Kodadi, M.; ET-Touhami, A.; Yahyi, A.; Yousfi, E.B.; Touzani, R.; Siaj, M. New Catalysts Based on Carboxylate Sn(IV) Complexes Used in the Oxidation Reaction of 3,5-Di-Tert-Butylcatechol to 3,5-Di-Tert-Butyl-o-Benzoquinone. Reaction Kinetics, Mechanisms and Catalysis 2023, doi:10.1007/s11144-023-02525-6. Titi, A.; Dahmani, M.; Abbaoui, Z.; El Kodadi, M.; ET-Touhami, A.; Yahyi, A.; Yousfi, E.B.; Touzani, R.; Siaj, M. New Catalysts Based on Carboxylate Sn(IV) Complexes Used in the Oxidation Reaction of 3,5-Di-Tert-Butylcatechol to 3,5-Di-Tert-Butyl-o-Benzoquinone. Reaction Kinetics, Mechanisms and Catalysis 2023, doi:10.1007/s11144-023-02525-6.

Abstract

It is at the chemistry-biology interface that this work that we have carried out takes place. Indeed, the expected goal is to develop simple molecules, capable of activating the catalytic action of certain metalloenzymes such as tyrosinase. The official name of an enzyme includes the type of reaction catalyzed, the name of the substrates involved. In this work, we carried out the study of the catalytic activity of the complexes of organotin carboxylates synthesized vis-à-vis the oxidation of 3,5-di-tert-butylcatecchol. The results obtained show that the various complexes exhibit good catalytic activity for the oxidation of 3,5-di-tert-butylcatecchol under mild conditions. The complexes that showed good catalytic activity are the compounds C1 and C2.

Keywords

Di-Carboxylate; Pyrazole; Tin Sn(VI); Crystal Structres; Oxidation Reaction.

Subject

Chemistry and Materials Science, Organic Chemistry

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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