Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Dielectric Properties of Aqueous Solutions at Normal and High Dilutions

Version 1 : Received: 1 March 2022 / Approved: 3 March 2022 / Online: 3 March 2022 (13:52:45 CET)

How to cite: Savel’ev, S.V.; Morozova, L.A. Dielectric Properties of Aqueous Solutions at Normal and High Dilutions. Preprints 2022, 2022030065. https://doi.org/10.20944/preprints202203.0065.v1 Savel’ev, S.V.; Morozova, L.A. Dielectric Properties of Aqueous Solutions at Normal and High Dilutions. Preprints 2022, 2022030065. https://doi.org/10.20944/preprints202203.0065.v1

Abstract

Using an original method for measuring weak radiothermal electromagnetic signals, experimental data were obtained on the analysis of dispersions of noise attractors of the radiobrightness temperature of aqueous solutions of NaCl, Al (NO₃)3 at dilutions C1 (1:100) – C12 (12:100). The values of dispersions of noise attractors significantly differ from those for the control experiment with water. On the basis of the changed values of the noise attractors of the radiobrightness temperature, the values of the absorption coefficients of the solutions are calculated. The difference between the values of the solutions absorption coefficients and those for water is shown with a successive increase in their values with an increase in the degree of dilution. The difference between the values of the absorption coefficients of solutions of high dilutions and those for water is interpreted as a mechanism of cooperative interaction of ions with water molecules located outside the first hydration shell. A network of water molecules perturbed by ions contributes to the dielectric permittivity was obtained due to new properties at supramolecular interactions on the basis of dispersion interaction.

Keywords

radiothermal signals; radiobrightness temperature; normal and high dilution solutions; absorption coefficient; ion hydration shell; new dielectric properties; supramolecular interactions; dispersion

Subject

Physical Sciences, Fluids and Plasmas Physics

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