Carbones and Carbon Atom as Ligands in Transition Metal Complexes

Lili Zhao; Chaoqun Chai; Wolfgang Petz; Gernot Frenking

Working Paper Review Version 1 This version is not peer-reviewed

Version 1 : Received: 23 August 2020 / Approved: 25 August 2020 / Online: 25 August 2020 (04:16:15 CEST)

This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M] CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C.

carbone complexes; carbido complexes; transition metal complexes; chemical bonding

Chemistry and Materials Science, Theoretical Chemistry

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Carbones and Carbon Atom as Ligands in Transition Metal Complexes

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