A Reversible Protonic Ceramic Cell with Symmetrically Designed Pr2NiO4+&delta;-Based Electrodes: Fabrication and Electrochemical Features

Artem Tarutin; Julia Lyagaeva; Andrey Farlenkov; Sergey Plaksin; Gennady Vdovin; Anatoly Demin; Dmitry Medvedev

doi:10.20944/preprints201811.0572.v1

Preprint Article Version 1 This version is not peer-reviewed

A Reversible Protonic Ceramic Cell with Symmetrically Designed Pr₂NiO_4+δ-Based Electrodes: Fabrication and Electrochemical Features

Artem Tarutin , Julia Lyagaeva , Andrey Farlenkov , Sergey Plaksin , Gennady Vdovin , Anatoly Demin , Dmitry Medvedev ^*

Version 1 : Received: 23 November 2018 / Approved: 26 November 2018 / Online: 26 November 2018 (06:42:08 CET)
Version 2 : Received: 20 December 2018 / Approved: 20 December 2018 / Online: 20 December 2018 (05:23:10 CET)

A peer-reviewed article of this Preprint also exists.

Tarutin, A.; Lyagaeva, J.; Farlenkov, A.; Plaksin, S.; Vdovin, G.; Demin, A.; Medvedev, D. A Reversible Protonic Ceramic Cell with Symmetrically Designed Pr₂NiO_4+δ-Based Electrodes: Fabrication and Electrochemical Features. Materials 2019, 12, 118. Tarutin, A.; Lyagaeva, J.; Farlenkov, A.; Plaksin, S.; Vdovin, G.; Demin, A.; Medvedev, D. A Reversible Protonic Ceramic Cell with Symmetrically Designed Pr2NiO4+δ-Based Electrodes: Fabrication and Electrochemical Features. Materials 2019, 12, 118.

Journal reference: Materials 2019, 12, 118
DOI: 10.3390/ma12010118

Abstract

Reversible protonic ceramic cells (rPCCs) combine two different operation regimes, fuel and electrolysis modes, which allow reversible chemical-to-electrical energy conversion at reduced temperatures with high efficiency and performance. Here we present novel technological and materials science approaches, enabling a rPCC with symmetrical functional electrodes to be prepared using a single sintering step. The response of the cell fabricated on the basis of P–N–BCZD|BCZD|PBN–BCZD (where BCZD = BaCe_0.5Zr_0.3Dy_0.2O_3–δ, PBN = Pr_1.9Ba_0.1NiO_4+δ, P = Pr₂O₃, N = Ni) is studied at different temperatures and water vapor partial pressures by means of volt-ampere measurements, electrochemical impedance spectroscopy and distribution of relaxation times analyses. The obtained results demonstrate that symmetrical electrodes exhibit classical mixed-ionic/electronic conducting behavior with no hydration capability at 750 °C; therefore, increasing the pH₂O values in both reducing and oxidizing atmospheres leads to some deterioration of their electrochemical activity. At the same time, the electrolytic properties of the BCZD membrane are improved, positively affecting the rPCC’s efficiency. The electrolysis mode of the rPCC is found to be more efficient than the fuel cell mode under highly humidified atmospheres, since its performance is determined by the ohmic resistance, which decreases under respectively less humid conditions.

Subject Areas

PCFCs/PCECs; ruddlesden-popper phases; symmetrical cells; proton-conducting electrolytes

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Download PDF

Comments (0)

Your full name

Your affiliation information (e.g., name of your university/institution/organization)

Not displayed online.

Your Email address (not made public)

Please leave your comment to this article below.

Mathematical equations can be typed in either LaTeX formats \\[ ... \\] or $$ ... $$, or MathML format <math> ... </math>. Try the LaTeX or MathML example.

Type equation:

Preview:

Copy equation into message below

Close menu

Please click a symbol to insert it into the message box below:

Please enter the link here:

Optionally, you can enter text that should appear as linked text:

Copy link into message below

Close menu

Please enter or paste the URL to the image here (please only use links to jpg/jpeg, png and gif images):

Copy image into message below

Close menu

Type author name or keywords to filter the list of references in this group (you can add a new citation under Bibliography):

No existing citations in Discussion Group

Wikify editor is a simple editor for wiki-style mark-up. It was written by MDPI for Sciforum in 2014. The rendering of the mark-up is based on Wiky.php with some tweaks. Rendering of mathematical equations is done with MathJax. Please send us a message for support or for reporting bugs.

Close menu

Please declare any conflicts of interest you may have with this paper, financial or otherwise.

I do not have a conflict of interest

I would like to declare a conflict of interest

Display my name on the website I want to get recognition for my comment on Publons

[what’s this?]. Link your accounts here

Captcha

Renew

I accept the following conditions:

Comments must follow the standards of professional discourse and should focus on the scientific content of the article. Insulting or offensive language, personal attacks and off-topic remarks will not be permitted. Comments must be written in English. Preprints reserves the right to remove comments without notice. Readers who post comments are obliged to declare any competing interests, financial or otherwise.

We encourage comments and feedback from a broad range of readers. See criteria for comments and our diversity statement.

Leave a public comment
Send a private comment to the author(s)

Get PDF Cite Share

Bookmark BibSonomy Mendeley Reddit Delicious Publons

Alerts

Notify me about updates to this article or when a peer-reviewed version is published.