Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy

Mario Pagliaro; Alexandra Fidalgo; Leonardo Palmisano; Laura M. Ilharco; Francesco Parrino; Rosaria Ciriminna

doi:10.20944/preprints201804.0067.v1

A peer-reviewed article of this Preprint also exists.

Parrino, F.; Fidalgo, A.; Palmisano, L.; Ilharco, L. M.; Pagliaro, M.; Ciriminna, R. Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy. ACS Omega, 2018, 3, 4884–4890. https://doi.org/10.1021/acsomega.8b00644. Parrino, F.; Fidalgo, A.; Palmisano, L.; Ilharco, L. M.; Pagliaro, M.; Ciriminna, R. Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy. ACS Omega, 2018, 3, 4884–4890. https://doi.org/10.1021/acsomega.8b00644.

Abstract

Limonene epoxide (1,2 limonene oxide) readily reacts with carbon dioxide in a ring opening copolymerization reaction with insertion of CO₂ and formation of polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy.

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Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy

Abstract

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Subject

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