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Silica Modified by Using Alcohol Polyoxyethylene Ether and Silane Coupling Agent together to Achieve High Performance Rubber Composites Using Latex Compounding Method
Zheng, J.; Ye, X.; Han, D.; Zhao, S.; Wu, X.; Wu, Y.; Dong, D.; Wang, Y.; Zhang, L. Silica Modified by Alcohol Polyoxyethylene Ether and Silane Coupling Agent Together to Achieve High Performance Rubber Composites Using the Latex Compounding Method. Polymers2018, 10, 1.
Zheng, J.; Ye, X.; Han, D.; Zhao, S.; Wu, X.; Wu, Y.; Dong, D.; Wang, Y.; Zhang, L. Silica Modified by Alcohol Polyoxyethylene Ether and Silane Coupling Agent Together to Achieve High Performance Rubber Composites Using the Latex Compounding Method. Polymers 2018, 10, 1.
Zheng, J.; Ye, X.; Han, D.; Zhao, S.; Wu, X.; Wu, Y.; Dong, D.; Wang, Y.; Zhang, L. Silica Modified by Alcohol Polyoxyethylene Ether and Silane Coupling Agent Together to Achieve High Performance Rubber Composites Using the Latex Compounding Method. Polymers2018, 10, 1.
Zheng, J.; Ye, X.; Han, D.; Zhao, S.; Wu, X.; Wu, Y.; Dong, D.; Wang, Y.; Zhang, L. Silica Modified by Alcohol Polyoxyethylene Ether and Silane Coupling Agent Together to Achieve High Performance Rubber Composites Using the Latex Compounding Method. Polymers 2018, 10, 1.
Abstract
Nowadays, the study of preparing silica/rubber composites, which can be used in “green tire”, in energy saving method is fast-growing. In our work, silica modified by using alcohol polyoxyethylene ether (AEO) and 3-Mercaptopropyltriethoxysilane (K-MEPTS) together were investigated. Thermal gravimetric analyzer (TGA) result indicated that both AEO and K-MEPTS could be grafted on the silica surface. Raman spectroscopy confirmed that the AEO could generate a certain steric hindrance for the mercaptopropyl group on K-MEPTS. Silica modified by using AEO and K-MEPTS together can be completely co-coagulated with the rubber in preparing silica/natural rubber (NR) composites by latex compounding method. AEO can form a physical interface between silica and rubber; meanwhile, K-MEPTS can form a chemical interface between silica and rubber. The effects of chemical and physical interface between silica and rubber on dynamic and mechanical performances of silica/NR composites were also given in this research. A proper combination of physical and chemical interface between silica and NR can improve performances of silica/NR composites.
Keywords
chemical and physical interface; surface modification of silica; latex compounding method; silica/NR composite
Subject
CHEMISTRY, Applied Chemistry
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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