Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry2016, 2, 46.
Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.
Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry2016, 2, 46.
Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.
Abstract
During the last years there has been a high interest in the development of new purely-organic single-component conductors. Very recently, we have reported a new neutral radical conductor based on the perchlorotriphenylmethyl (PTM) radical moiety linked to a monopyrrolo-tetrathiafulvalene (MPTTF) unit by a -conjugated bridge (1). Interestingly, this system behaves as a semiconductor with high conductivity and small energy gap under high pressure. With the aim of developing a new material with improved conducting properties, we have designed and synthesized the radical dyad 2 which was functionalized with an ethylenedithio (EDT) group in order to improve the intermolecular interactions of the TTF subunits. The physical properties of the new radical dyad 2 were studied in detail in solution to further analyze its electronic structure as well as its potential use as radical conductor in the solid state.
Chemistry and Materials Science, Physical Chemistry
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