Synthesis and Characterization of Dibutyltin Compounds with &alpha;-Amino Acids

Roberto Santos Barbiéri; Vilma Reis Terra; Allan Kardec Carlos Dias; Walclée De Carvalho Melo; Daniel Rodrigues Silva

doi:10.20944/preprints201608.0239.v1

How it Works
Instructions for Authors
Subject Areas
Advisory Board
About

Advanced Search

Submit preprint Login Register

Share this article with

Create alert

Email:

Load new image

preprints.org > chemistry > organic chemistry > doi: 10.20944/preprints201608.0239.v1

Preprint Article Version 1 NOT YET PEER-REVIEWED

Synthesis and Characterization of Dibutyltin Compounds with α-Amino Acids

Roberto Santos Barbiéri , Vilma Reis Terra , Allan Kardec Carlos Dias , Walclée De Carvalho Melo , Daniel Rodrigues Silva ^*

Version 1 : Received: 30 August 2016 / Approved: 31 August 2016 / Online: 31 August 2016 (10:43:02 CEST)

How to cite: Santos Barbiéri, R.; Reis Terra, V.; Carlos Dias, A.; De Carvalho Melo, W.; Rodrigues Silva, D. Synthesis and Characterization of Dibutyltin Compounds with α-Amino Acids. Preprints 2016, 2016080239 (doi: 10.20944/preprints201608.0239.v1). Santos Barbiéri, R.; Reis Terra, V.; Carlos Dias, A.; De Carvalho Melo, W.; Rodrigues Silva, D. Synthesis and Characterization of Dibutyltin Compounds with α-Amino Acids. Preprints 2016, 2016080239 (doi: 10.20944/preprints201608.0239.v1).

Cite as:

Santos Barbiéri, R.; Reis Terra, V.; Carlos Dias, A.; De Carvalho Melo, W.; Rodrigues Silva, D. Synthesis and Characterization of Dibutyltin Compounds with α-Amino Acids. Preprints 2016, 2016080239 (doi: 10.20944/preprints201608.0239.v1). Santos Barbiéri, R.; Reis Terra, V.; Carlos Dias, A.; De Carvalho Melo, W.; Rodrigues Silva, D. Synthesis and Characterization of Dibutyltin Compounds with α-Amino Acids. Preprints 2016, 2016080239 (doi: 10.20944/preprints201608.0239.v1).

Abstract

This paper describes the preparation and description of four new complexes [Bu₂Sn(AA)Cl] (AA = glycine, DL-valine and L-leucine) and [Bu₂SnPhen₂] (Phen = DL-phenylalanine) They were characterized by elemental analyses of carbon, hydrogen, nitrogen, chlorine and tin; and by infrared, ^119mSn-Mössbauer and ^119mSn-RMN spectroscopies, and by the applications of TG and DSC techniques in dynamic helium atmosphere. For the [Bu₂Sn(AA)Cl], trigonal bipyramidal tin species, AA were coordinated bidentatedly by the carboxylic oxygen and by the NH₂ group. The [Bu₂SnPhen₂)], with tin atoms in trans-octahedral sites, had the Phen-coordinated by both carboxylic oxygen atoms.

Subject Areas

organotin compounds; dibutyltin compounds; tin α-amino acids compounds; thermal decomposition

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Get PDF Cite Share

Readers' Comments and Ratings (0)

Your full name

Your affiliation information (e.g., name of your university/institution/organization)

Not displayed online.

Your Email address (not made public)

Importance: How significant is the paper to the field?

Outstanding/highlight paper

Significant contribution

Incremental contribution

No contribution

I am not qualified to judge

Soundness of evidence/arguments presented:

Conclusions well supported

Most conclusions supported (minor revision needed)

Incomplete evidence (major revision needed)

Hypothesis, unsupported conclusions, or proof-of-principle

I am not qualified to judge

Please leave your comment to this article below.

Mathematical equations can be typed in either LaTeX formats \\[ ... \\] or $$ ... $$, or MathML format <math> ... </math>. Try the LaTeX or MathML example.

Type equation:

Preview:

Copy equation into message below

Close menu

Please click a symbol to insert it into the message box below:

Please enter the link here:

Please enter a valid URL

Optionally, you can enter text that should appear as linked text:

Copy link into message below

Close menu

Please enter or paste the URL to the image here (please only use links to jpg/jpeg, png and gif images):

Please enter a valid URL

Copy image into message below

Close menu

Type author name or keywords to filter the list of references in this group (you can add a new citation under Bibliography):

No existing citations in Discussion Group

Wikify editor is a simple editor for wiki-style mark-up. It was written by MDPI AG for Sciforum in 2014. The rendering of the mark-up is based on Wiky.php with some tweaks. Rendering of mathematical equations is done with MathJax. Please send us a message for support or for reporting bugs.

Close menu

Please declare any conflicts of interest you may have with this paper, financial or otherwise.

I do not have a conflict of interest

I would like to declare a conflict of interest

Display my name on the website Send my name and email address to the authors I want to get recognition for my comment on Publons

[what’s this?]. Link your accounts here I accept the following conditions:

Comments must follow the standards of professional discourse and should focus on the scientific content of the article. Insulting or offensive language, personal attacks and off-topic remarks will not be permitted. Comments must be written in English. Preprints reserves the right to remove comments without notice. Readers who post comments are obliged to declare any competing interests, financial or otherwise.

Leave a public comment
Send a private comment to the author(s)
Rate this article