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Chemical Reactions as Topological Hyperstructures: A Topological Reformulation of the Hyperstructural Model of Redox Reactions

Submitted:

15 October 2026

Posted:

16 October 2026

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Abstract
The hyperstructural model of redox reactions organises the oxidation states of an element into an Hv-group whose hyperoperation returns the set of thermodynamically accessible products. We recast this model in the language of general topology. To every hyperoperation ⊕ on a nite set H we attach a topology τ⊕, the reaction topology, generated by the family of hyperproducts {x ⊕ y} as a subbasis. We prove that τ⊕ is an Alexandrov topology whose minimal neighbourhoods are N(x) = ∩ {x ⊕ y : x ∈ x ⊕ y}; that its specialisation preorder admits the chemical reading y accompanies x in every reaction product containing x''; that τ⊕ is T0 exactly when no two species are reactionindistinguishable, and discrete exactly when every species is separated from all others by some reaction; and that the connected components of (H, τ⊕) are the components of the comparability graph of that preorder. We then show that the hyperoperation is continuous for the Vietoris hyperspace topology whenever it is constant on minimal neighbourhoods, so that every Hv-group with discrete reaction topology is a topological Hv-group, and that the quotient by the fundamental relation β∗ is discrete if and only if the β∗-classes are open. The constructions are worked out on the redox data for tin, iron, copper and manganese: the hypergraphs induced by the iron Hv-group yield, respectively, a disconnected space with components {Fe3+} and {Fe, Fe2+}, a connected T0 space, a connected non-T0 space with two Kolmogorov classes, and an indiscrete space, while the copper hypergraph yields a connected, non-discrete T0 space.
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