Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Estimation of Environmental Effects and Response Time in Gas Phase Explosives Detection Using Photoluminescence Quenching Method

Version 1 : Received: 12 February 2024 / Approved: 12 February 2024 / Online: 12 February 2024 (11:47:25 CET)

A peer-reviewed article of this Preprint also exists.

Noh, D.; Oh, E. Estimation of Environmental Effects and Response Time in Gas-Phase Explosives Detection Using Photoluminescence Quenching Method. Polymers 2024, 16, 908. Noh, D.; Oh, E. Estimation of Environmental Effects and Response Time in Gas-Phase Explosives Detection Using Photoluminescence Quenching Method. Polymers 2024, 16, 908.

Abstract

Detecting the presence of explosives is important to protect human lives in military conflicts and peacetime. Gas-phase detection of explosives can make use of the change of material properties, which can be sensitive to environmental conditions such as temperature and humidity. This paper describes a remote-controlled automatic shutter method for environmental impact assessment of photoluminescence (PL) sensors under near-open conditions. Utilizing the remote-sensing method, we obtained environmental effects without being exposed to sensing vapor molecules, and explained how PL intensity was influenced by the temperature, humidity, and exposure time. We also developed a theoretical model including the effect of exciton diffusion for PL quenching, which worked well under limited molecular diffusions. Incomplete recovery of PL intensity, or degradation effect, was considered as an additional factor in the model.

Keywords

explosives detection; environmental effects; photoluminescence; conjugated polymer; chemical sensing

Subject

Chemistry and Materials Science, Polymers and Plastics

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