Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Analysis of a Dynamic Model for Post-Combustion CO2 Capture on a Hollow Fiber Membrane Contactor

Version 1 : Received: 28 December 2023 / Approved: 29 December 2023 / Online: 29 December 2023 (13:49:45 CET)

How to cite: Passos, W.; Júnior, A.; Filho, J.; Rojas, L. Analysis of a Dynamic Model for Post-Combustion CO2 Capture on a Hollow Fiber Membrane Contactor. Preprints 2023, 2023122309. https://doi.org/10.20944/preprints202312.2309.v1 Passos, W.; Júnior, A.; Filho, J.; Rojas, L. Analysis of a Dynamic Model for Post-Combustion CO2 Capture on a Hollow Fiber Membrane Contactor. Preprints 2023, 2023122309. https://doi.org/10.20944/preprints202312.2309.v1

Abstract

The Hollow fiber membrane contactor (HFMC) is an intensification process that combines membrane and absorption technologies, being a technology in expansion, so the dynamics of this process is crucial for an increase in industrial scale-up. In this manuscript a rigorous dynamic model of an HFMC is developed and simulated in Python software for the absorption of post-combustion CO2 using a monoethanolamine (MEA) solution, which was validated using available data in literature in steady state. Dynamic simulations were performed to analyze the model's capability to predict the effect of disturbances on the responses of CO2 capture ratio and loading. Four distinct experiments were conducted by step changes and pulse disturbances at the following variables: gas and liquid volumetric flow rates, CO2 composition in flue gases, and CO2 lean load. The gas phase showed a faster response compared to the liquid. The CO2 capture ratio and rich loading presented opposite responses when disturbing both liquid flows, and for the composition and lean loading variations, the capture ratio presented an inverse response characteristic, while the loading showed a delayed response. As the model proved to be capable of returning to the reference state, it can potentially be used for control studies purposes.

Keywords

HFMC; carbon capture; modelling, and simulation; system dynamics; post-combustion

Subject

Engineering, Chemical Engineering

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