Martin, N.; Cote, J.-M.; Gavoille, J.; Potin, V. Tantalum Oxide Thin Films Sputter-Deposited by Oxygen Gas Pulsing. Coatings2023, 13, 1932.
Martin, N.; Cote, J.-M.; Gavoille, J.; Potin, V. Tantalum Oxide Thin Films Sputter-Deposited by Oxygen Gas Pulsing. Coatings 2023, 13, 1932.
Martin, N.; Cote, J.-M.; Gavoille, J.; Potin, V. Tantalum Oxide Thin Films Sputter-Deposited by Oxygen Gas Pulsing. Coatings2023, 13, 1932.
Martin, N.; Cote, J.-M.; Gavoille, J.; Potin, V. Tantalum Oxide Thin Films Sputter-Deposited by Oxygen Gas Pulsing. Coatings 2023, 13, 1932.
Abstract
Tantalum oxide thin films are deposited by DC reactive magnetron sputtering from a tantalum metallic target and oxygen as reactive gas. The reactive gas pulsing process (RGPP) is implemented to produce TaOx compounds with tunable chemical compositions. The argon mass flow rate is maintained constant whereas that of the oxygen gas is pulsed during the deposition. A constant pulsing period T = 10 s is used and the introduction time of the oxygen gas, namely the tON injection time, is systematically changed from 0 to 100 % of the pulsing period T. As the tON injection time increases, the chemical composition of as-deposited TaOx films is continuously changed from pure metallic tantalum to the over-stoichiometric Ta2O5 material. Analysis of the crystallographic structure by X-ray diffraction shows that the films adopt the body-centered cubic structure (metallic Ta) for the lowest tON injection time values (oxygen stoichiometry x < 1.0) and become amorphous for the longest tON injection times. It is shown that the tON injection time is a key parameter to produce either homogeneous tantalum oxides, or periodic Ta/TaOx multilayers with alternations close to 3 nm. Similarly, optical transmittance spectra of the film/glass substrate system are recorded in the visible region and the electrical conductivity of the films is measured vs. temperature. Both exhibit a gradual evolution from metallic (300K = 8.17105 S m-1 with a null optical transmittance in the visible range) to semi-conducting (300K = 1.97103 S m-1 with a semi-transparent behavior) and finally to dielectric properties (300K < 10-5 S m-1 for interferential films) as a function of the oxygen concentration in the films.
Chemistry and Materials Science, Materials Science and Technology
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