Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Formation of Cu Nanotwins on Silicon Carbide Wafers with Cr Adhesive Layer in Different Substrate Bias

Version 1 : Received: 19 September 2023 / Approved: 20 September 2023 / Online: 21 September 2023 (04:58:01 CEST)

A peer-reviewed article of this Preprint also exists.

Syafei, D.I.; Chiang, M.-T.; Chuang, T.-H. Formation of Cu Nanotwins on Silicon Carbide Wafers with Cr Adhesive Layer under Various Substrate Bias. Metals 2023, 13, 1747. Syafei, D.I.; Chiang, M.-T.; Chuang, T.-H. Formation of Cu Nanotwins on Silicon Carbide Wafers with Cr Adhesive Layer under Various Substrate Bias. Metals 2023, 13, 1747.

Abstract

This study focuses on the analyses of nano-twinned Copper (Cu) films deposited through magnetron sputtering on Silicon Carbide (SiC) chips. The investigation encompasses the utilization of Chromium (Cr) adhesive layer coupled with varying voltage bias conditions. The goal is to comprehensively examine the influence of adhesive layer and negative bias voltages, contributing to an enhanced understanding of materials engineering and bonding technologies for advanced applications. The formation of a nanotwinned structure and (111) surface orientation can be properly controlled by applied substrate bias. High density nanotwinned structures were introduced into Cu films sputtered on SiC substrates with 82.3% of (111)-orientation proportion at -150 V much higher than the Cu film sputtered with another substrate bias. It is concluded that the sputtered Cu nanotwinned film formed with -150 V bias voltage has the potential to be employed as the interlayer for low temperature direct bonding.

Keywords

Cu nanotwin; Cr adhesive layer; magnetron sputtering; substrate bias

Subject

Engineering, Metallurgy and Metallurgical Engineering

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