Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Synthesis and Evaluation of Antifungal and Antibacterial Abilities of Carbon Nanotubes Grafted to Poly(2-hydroxyethyl methacrylate) Nanocomposites

Version 1 : Received: 2 August 2023 / Approved: 3 August 2023 / Online: 3 August 2023 (11:38:26 CEST)

A peer-reviewed article of this Preprint also exists.

Sandoval-García, K.; Alvarado-Mendoza, A.G.; Orozco-Guareño, E.; Olea-Rodríguez, M.A.; Cajero-Zul, L.R.; Nuño-Donlucas, S.M. Synthesis and Evaluation of Antifungal and Antibacterial Abilities of Carbon Nanotubes Grafted to Poly(2-hydroxyethyl methacrylate) Nanocomposites. Polymers 2023, 15, 3657. Sandoval-García, K.; Alvarado-Mendoza, A.G.; Orozco-Guareño, E.; Olea-Rodríguez, M.A.; Cajero-Zul, L.R.; Nuño-Donlucas, S.M. Synthesis and Evaluation of Antifungal and Antibacterial Abilities of Carbon Nanotubes Grafted to Poly(2-hydroxyethyl methacrylate) Nanocomposites. Polymers 2023, 15, 3657.

Abstract

Developing nanomaterials with the capacity to restrict the growth of bacteria and fungus is of current interest. In this study, nanocomposites of poly(2-hydroxyethyl methacrylate) (PHEMA) and carbon nanotubes (CNTs) functionalized with primary amine, hydroxyl, and carboxyl groups were prepared, and characterized. An analysis by Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy showed that PHEMA chains were grafted to the functionalized CNTs. The morphology of the prepared nanocomposites studied by field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM) shows significant changes with respect to the observed for pure PHEMA. The thermal behavior of the nanocomposites studied by differential scanning calorimetry (DSC) revels that the functionalized CNTs affects strongly the mobility of the PHEMA chains. Tests carried out by thermogravimetric analysis (TGA) were used to calculate the degree of grafting of the PHEMA chains. The ability of prepared nanocomposites to inhibit the growth of the fungus Candida albicans, and the bacteria Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia coli was evaluated. A moderated antifungal and antibacterial capacity of the prepared nanocomposites was determined.

Keywords

carbon nanotubes; nanocomposites; poly(2-hydroxyethyl methacrylate); antifungal capacity; antibacterial ability

Subject

Chemistry and Materials Science, Ceramics and Composites

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