Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Exploring Cobalt Doping Methods for Enhancing Blue-TiO2 Catalyst Efficiency

Version 1 : Received: 10 July 2023 / Approved: 10 July 2023 / Online: 11 July 2023 (09:25:55 CEST)

How to cite: Irodia, R.; Ungureanu, C.; Sătulu, V.; Mîndroiu, V.M. Exploring Cobalt Doping Methods for Enhancing Blue-TiO2 Catalyst Efficiency. Preprints 2023, 2023070653. https://doi.org/10.20944/preprints202307.0653.v1 Irodia, R.; Ungureanu, C.; Sătulu, V.; Mîndroiu, V.M. Exploring Cobalt Doping Methods for Enhancing Blue-TiO2 Catalyst Efficiency. Preprints 2023, 2023070653. https://doi.org/10.20944/preprints202307.0653.v1

Abstract

This study presents a straightforward electrochemical and plasma deposition method for producing Cobalt-doped Blue-TiO2 nanotubes with enhanced catalytic properties. After a titanium plate has been anodized, specific procedures are carried out that cause oxygen vacancies to form inside the TiO2 nanostructures. The obtained catalysts were subjected to electrochemical tests (to identify charge transfer resistance and flat band potential), optical analysis (to determine the band gap and Urbach energy) and also characterized in terms of morphology, wettability and antibacterial effect in order to understand and analyze the impact of the Co doping method on the final catalyst characteristics. A hydrophilic film with star-shaped structures and with antibacterial effect was created when cobalt was electrochemically doped to Blue-TiO2 nanotubes. By using this electrochemical doping technique, the Urbach energy was raised from 1.171 to 3.836 eV while the band gap energy was decreased from 3.04 to 2.88 eV. Additionally, photodegradation experiments using artificial doxycycline (DOX) water were conducted to determine the practical relevance of the research findings. In areas like antimicrobial applications and photodegradation of DOX, these extra experiments aimed to show the practical applicability and potential advantages of the research findings.

Keywords

Nanostructures; Blue-TiO2 nanotubes; Antimicrobial; Antibiotics; Photocatalytic

Subject

Environmental and Earth Sciences, Water Science and Technology

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