Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Phytochemical Substances —Mediated Synthesis of Zinc Oxide Nanoparticles (ZnO NPS)

Version 1 : Received: 4 July 2023 / Approved: 5 July 2023 / Online: 5 July 2023 (12:32:59 CEST)

A peer-reviewed article of this Preprint also exists.

Alharbi, F.N.; Abaker, Z.M.; Makawi, S.Z.A. Phytochemical Substances—Mediated Synthesis of Zinc Oxide Nanoparticles (ZnO NPS). Inorganics 2023, 11, 328. Alharbi, F.N.; Abaker, Z.M.; Makawi, S.Z.A. Phytochemical Substances—Mediated Synthesis of Zinc Oxide Nanoparticles (ZnO NPS). Inorganics 2023, 11, 328.

Abstract

Artemisia absinthium (A. absinthium) leaf extract was successfully used to create zinc oxide nanoparticles (ZnO NPs), and their properties were investigated via several techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), Fourier transform infrared (FTIR), and UV–Vis spectroscopy. SEM analysis confirmed the spherical and elliptical shapes of the particles. Three different zinc peaks were observed via EDX at energies of 1, 8.7, and 9.8 keV, together with a single oxygen peak at 0.5 keV. XRD analysis identified ZnO NPs as having a hexagonal wurtzite structure with a particle size that decreased from 24.39 to 18.77 nm, and with an increasing surface area (BET) from 4.003 to 6.032 m2/g for the ZnO (without extract) and green ZnO NPs, respectively. FTIR analysis confirmed the groups of molecules that were accountable for stabilizing and minimizing the ZnO NPs, which was apparent at 3400 cm. Using UV–Vis spectroscopy, the band gap energies (Egs) for the green ZnO and ZnO (without extract) NPs were estimated, and the values were 2.65 and 2.79 eV, respectively.

Keywords

Artemisia absinthium; green ZnO NPs; band gap energy; plant extract; phytochemicals

Subject

Chemistry and Materials Science, Nanotechnology

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