Ben, F., & Olubambi, P. A. (2023). Thermo-Calc determination of phase diagram and thermodynamic properties of Ni-Al binary system. Materials Today: Proceedings.
Ben, F., & Olubambi, P. A. (2023). Thermo-Calc determination of phase diagram and thermodynamic properties of Ni-Al binary system. Materials Today: Proceedings.
Ben, F., & Olubambi, P. A. (2023). Thermo-Calc determination of phase diagram and thermodynamic properties of Ni-Al binary system. Materials Today: Proceedings.
Ben, F., & Olubambi, P. A. (2023). Thermo-Calc determination of phase diagram and thermodynamic properties of Ni-Al binary system. Materials Today: Proceedings.
Abstract
Ni-Al alloys have good corrosion-resistant properties making them preferable as a material of choice compared to ordinary metals. A good understanding of the phase diagram and thermodynamic properties of the Ni-Al alloy binary system is essential in determining relevant industrial applications of the system. The Ni-Al phase diagram is being reassessed since those found in the literatures are based on very old experimental studies. The phase diagram and thermodynamic properties of the Ni-Al alloy is determined using the Thermo-Calc 2022b software over a temperature range of 200 K to 2000 K and 1 atm of pressure. A total of nineteen fields (including elemental Al and Ni) comprising of five single solid phases, one liquid phase, and twelve double regions was obtained from the equilibrium calculation. The thermodynamic calculation has six invariant reactions comprising of two eutectic reactions (914.83 ± 0.025 K and 1641.80 ± 0.025 K), three peritectic reactions (1123.55 ± 0.025 K, 1400.72 ± 0.025 K and 1642.65 ± 0.025 K), and one peritectoid reaction (913.96 ± 0.025 K). The solubility of Al in Ni is also determined. The Thermo-Calc temperature – composition of the Ni-Al alloy is compared with the existing experimental studies to identify the physical properties of the different thermodynamic properties of the Ni-Al alloy binary system.
Engineering, Metallurgy and Metallurgical Engineering
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