Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Novel Co2Mn-Based Heusler Alloy Microwires with Promising Magnetization Thermal Stability for Multifunctional Applications

Version 1 : Received: 14 June 2023 / Approved: 15 June 2023 / Online: 15 June 2023 (07:29:04 CEST)

A peer-reviewed article of this Preprint also exists.

Salaheldeen, M.; Wederni, A.; Ipatov, M.; Zhukova, V.; Zhukov, A. Carbon-Doped Co2MnSi Heusler Alloy Microwires with Improved Thermal Characteristics of Magnetization for Multifunctional Applications. Materials 2023, 16, 5333. Salaheldeen, M.; Wederni, A.; Ipatov, M.; Zhukova, V.; Zhukov, A. Carbon-Doped Co2MnSi Heusler Alloy Microwires with Improved Thermal Characteristics of Magnetization for Multifunctional Applications. Materials 2023, 16, 5333.

Abstract

In current work, we illustrate the effect of adding small amount of Carbon to very common Co2MnSi Heusler alloy based-glass coated microwires. A significant change in the magnetic and structure structural properties has observed for the new alloy Co2MnSiC compared to the Co2MnSi alloy. The magneto-structural investigations have performed to clarify the main phys-ical parameters i.e., structural & magnetic at a wide range of measuring temperature. The XRD analysis illustrated the well-defined crystalline structure with average grain size (Dg = 29.16 nm) and a uniform cubic structure with A2-type compared to the mixed L21 and B2 cubic structures for Co2MnSi-based glass coated microwires. The magnetic behaviour has investigated at a tem-perature range (5 to 300 K) and an external applied magnetic field (50 Oe to 20 kOe). The adding of small amount of Carbon to the Co2MnSi matrix enhance the magnetic thermal stability, where the thermomagnetic behaviour of Co2MnSiC glass-coated microwires show a perfect stable be-haviour for a temperature range from 300 K to 5 k, the differences between the coercivity value is only 0.3 Oe compared to 4 Oe for Co2MnSi-sample. In addition, M-H loops measured at tempera-ture below 50 K show unsaturated loops; meanwhile the Co2MnSi loops shows a strong antifer-romagnetic coupling for the loops measured below 50 K. By studying the field cooling (FC) and field heating (FH) magnetizations curves at a wide range of external applied magnetic field we detected a critical magnetic field (H = 1 kOe) where FC and FH curves have a stable magnetic behavior for Co2MnSiC sample, such stability does not find in Co2MnSi sample. We proposed a phenomenal expression to estimate the magnetization thermal stability, ΔM (%), of FC and FH magnetization curves and the maximum value is detected at the critical magnetic field where ΔM (%) ≈ 98 %. The promising magnetic stability of Co2MnSiC glass-coated microwires with tem-perature is due to the changing of the microstructure induced by adding Carbon, as the A2-type structure show a unique stability by variation the temperature and the external magnetic field. In addition, a unique internal mechanical stress, which induced during the fabrication process and plays on controlling magnetic behavior with temperature and external magnetic field. The ob-tained results make Co2MnSiC promising candidate for magnetic sensing devices based Heusler glass-coated microwires.

Keywords

Heusler alloys; Glass-coated microwires; Thermal stability; Magnetic sensing; HR-TEM

Subject

Chemistry and Materials Science, Materials Science and Technology

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