Waste pollution represents an increasingly serious problem affecting the health and well-being of people living in many developing countries. Many studies have examined and recommended waste-reducing solutions, yet environmental culture-based measures remain understudied. This study employs a novel approach that integrates the Culture Tower with the Contingent Valuation Method and a Bayesian model (CVBM) to explore and advance households’ environmental culture associated with waste management. Specifically, descriptive statistics capture respondents’ environmental perceptions and literacy, while the Bayesian model and CVM identify the determinants of households’ willingness to pay (WTP) and estimate WTP for waste treatment service (WTP4WTS), respectively. We found that despite the observed reduction in local waste pollution over time, respondents maintain a persistent concern regarding this issue. Over 13% of the households surveyed expressed dissatisfaction with waste treatment services (WTS), contrasting with nearly 50% of households that reported a neutral perspective. We also found that a significant majority (79.26%) of respondents were willing to pay for WTS, with an average WTP of 60,200 VND (US$2.32) per month. Importantly, the primary predictors of WTP4WTS were found to be the desire for improved waste services, current perceived waste pollution, and the belief that pollution has worsened over time. These findings offer important policy implications for mobilizing untapped household-level resources to foster environmental culture, thereby strengthening financing for better waste treatment services and facilitating the clean and green transformation for sustainable development in Vietnam and beyond in the years to come.