Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Microstructure, Physical Properties and Oxidative Stability of Olive Oil Oleogels Composed of Sunflower Wax and Monoglycerides

Version 1 : Received: 15 February 2024 / Approved: 15 February 2024 / Online: 22 February 2024 (05:03:36 CET)

A peer-reviewed article of this Preprint also exists.

Dimakopoulou-Papazoglou, D.; Zampouni, K.; Prodromidis, P.; Moschakis, T.; Katsanidis, E. Microstructure, Physical Properties, and Oxidative Stability of Olive Oil Oleogels Composed of Sunflower Wax and Monoglycerides. Gels 2024, 10, 195. Dimakopoulou-Papazoglou, D.; Zampouni, K.; Prodromidis, P.; Moschakis, T.; Katsanidis, E. Microstructure, Physical Properties, and Oxidative Stability of Olive Oil Oleogels Composed of Sunflower Wax and Monoglycerides. Gels 2024, 10, 195.

Abstract

The utilization of natural waxes to form oleogels has emerged as a new and efficient technique for structuring liquid edible oil into solid-like structures for diverse food applications. The objective of this study was to investigate the interaction between sunflower wax (SW) and monoglycerides (MGs) in olive oil oleogels and to assess their physical characteristics and storage stability. To achieve this, pure SW and a combination of SW with MGs in a 1:1 ratio were examined within a total concentration range of 6-12% w/w. The formed oleogels were characterized based on their microstructure, melting and crystallization properties, textural characteristics, and oxidative stability during storage. All the oleogels were shelf-stable, and as the concentration increased, the hardness of the oleogels also increased. The crystals of SW oleogels were long needle-like, while the combination of SW and MGs led to the formation of crystal aggregates and rosette-like crystals. The differential scanning calorimetry and FTIR showed that the addition of MGs led to different crystal structures. The oxidation results revealed that oleogels had low peroxide and TBARS values throughout the 28-day storage. These results provide useful insights about the utilization of SW and MGs oleogels for potential applications in the food industry.

Keywords

oleogels; sunflower wax; lipid structuring; crystallization; FTIR; storage

Subject

Biology and Life Sciences, Food Science and Technology

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