Preprint Article Version 2 Preserved in Portico This version is not peer-reviewed

Preparation and corrosion resistance of Zn-Y2O3-Al2O3 nanocomposite coatings fabricated via electrodeposition

Version 1 : Received: 13 January 2024 / Approved: 15 January 2024 / Online: 15 January 2024 (07:12:28 CET)
Version 2 : Received: 15 January 2024 / Approved: 16 January 2024 / Online: 16 January 2024 (06:25:46 CET)

How to cite: Feng, X.; Qiu, F.; MOHAMED CONDE, S.; Dong, C.D. Preparation and corrosion resistance of Zn-Y2O3-Al2O3 nanocomposite coatings fabricated via electrodeposition . Preprints 2024, 2024011084. https://doi.org/10.20944/preprints202401.1084.v2 Feng, X.; Qiu, F.; MOHAMED CONDE, S.; Dong, C.D. Preparation and corrosion resistance of Zn-Y2O3-Al2O3 nanocomposite coatings fabricated via electrodeposition . Preprints 2024, 2024011084. https://doi.org/10.20944/preprints202401.1084.v2

Abstract

This article utilized electrodeposition technology to fabricate Zn and Zn-Y2O3-Al2O3 composite coatings on Q235 steel plates. The composite coatings were obtained by adding Y2O3/Al2O3 nanoparticles (0, 5, 10, and 15 g/L) to acidic chloride solutions. This study then examined the impact of these nanoparticles on the microstructure, morphology, microhardness, hydrophobicity, and corrosion resistance of the composite coatings. The results indicate that the addition of the nanoparticles increased the nucleation sites on the surface of the coating, thereby refining the grain size and reducing the roughness of the coating surface. When 10g/L of Y2O3 and 10g/L of Al2O3 nanoparticles were added, the hardness of the composite coating (369 Hv) was 2.49 times higher than that of the pure Zn coating (148 Hv), which was attributed to the dispersion strengthening and grain refinement effects of the nanoparticles. The corrosion resistance of the Zn and Zn-Y2O3-Al2O3 composite coatings was studied using linear sweep voltammetry and AC impedance spectroscopy. The addition of the nanoparticles improved the corrosion resistance of the composite coating, and the composite coating prepared in an electrolyte containing 10 g/L of Y2O3 and 10 g/L of Al2O3 nanoparticles exhibited the best corrosion resistance. Meanwhile, the composite coating exhibited good hydrophobicity, with a contact angle of 120.9°, 1.94 times that of the pure Zn coating (62.2°). The Zn-Y2O3-Al2O3 nanocomposite coating material has significant potential advantages in the field of steel corrosion.

Keywords

Electrodeposition; Zn-Y2O3-Al2O3; Nanocomposite; Corrosion; Microhardness

Subject

Engineering, Mining and Mineral Processing

Comments (1)

Comment 1
Received: 16 January 2024
Commenter: Xiujuan Feng
Commenter's Conflict of Interests: Author
Comment: NO
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