Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Amp-TB2 Protocol and Its Application to Amphiboles from Recent, Historical and Pre-historical Eruptions of Bezymianny Volcano, Kamchatka

Version 1 : Received: 29 September 2023 / Approved: 30 September 2023 / Online: 30 September 2023 (07:10:58 CEST)

A peer-reviewed article of this Preprint also exists.

Ridolfi, F.; Almeev, R.R.; Ozerov, A.Y.; Holtz, F. Amp-TB2 Protocol and Its Application to Amphiboles from Recent, Historical and Pre-Historical Eruptions of the Bezymianny Volcano, Kamchatka. Minerals 2023, 13, 1394. Ridolfi, F.; Almeev, R.R.; Ozerov, A.Y.; Holtz, F. Amp-TB2 Protocol and Its Application to Amphiboles from Recent, Historical and Pre-Historical Eruptions of the Bezymianny Volcano, Kamchatka. Minerals 2023, 13, 1394.

Abstract

This article reports a protocol on the application of Amp-TB2 (single-amphibole ther-mobarometry; [1]) based on detailed electron microprobe analyses performed on homogeneous natural standards and synthetic glasses, and amphibole crystals (mostly phenocrysts) of volcanic products erupted by Bezymianny volcano during its activity through time. The application of this protocol is facilitated by a new version of the model (Amp-TB2.1.xlsx) including an equation to identify heterogeneous domains (disequilibrium; not suitable for thermobarometric constraints) and homogenous (equilibrium) zones within amphibole crystals, which can be used to quantify the physico-chemical parameters (i.e., pressure, P; temperature, T; volatile content in the melt, H2Omelt; oxygen fugacity, fO2) of “steady-state” magmatic crystallization. Application examples of the protocol, showing detailed core-rim microprobe data and physico-chemical parameter variations in representative amphibole phenocrysts of Bezymianny are also reported. The depth (and P) estimated by Amp-TB2.1 for this volcano are compared to seismic tomography results. Amp-TB2.1 results mainly shows (1) that Bezymianny is characterized by a very dynamic feeding system where the magma is stored at shallow crustal levels before recent activity periods characterized by climatic events and (2) that the pre-eruptive depth of magma storage generally increases with the age of the investigated products.

Keywords

amphibole; thermobarometry; equilibrium crystallization; volcanoes; magma chamber; magma feeding system; seismic tomography

Subject

Environmental and Earth Sciences, Geochemistry and Petrology

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