Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Investigating Asphaltene Deposition Kinetics through Particle Size and Count Correlation

Version 1 : Received: 22 September 2023 / Approved: 25 September 2023 / Online: 25 September 2023 (11:03:08 CEST)

How to cite: Ali, M.; Adedamola Stephen, A. Investigating Asphaltene Deposition Kinetics through Particle Size and Count Correlation. Preprints 2023, 2023091646. https://doi.org/10.20944/preprints202309.1646.v1 Ali, M.; Adedamola Stephen, A. Investigating Asphaltene Deposition Kinetics through Particle Size and Count Correlation. Preprints 2023, 2023091646. https://doi.org/10.20944/preprints202309.1646.v1

Abstract

Asphaltene precipitation and deposition pose significant operational challenges in both reservoirs and surface facilities by inducing formation damage. To understand the kinetics involved in asphaltene particle nucleation, growth, and aggregation, this study employed confocal microscopy and centrifuge-based methods under a unified set of experimental parameters. The acquired time-resolved particle size images were analyzed using MIPAR image processing software, while asphaltene mass yield was quantitatively evaluated through centrifugation. Experimental conditions were varied to study the effects of heptane concentration, asphaltene concentration, and shear rate. Notably, this investigation introduces, for the first time, the parameter of particle count as an additional variable influencing asphaltene mass production. This study aims to discern how particle count correlates with asphaltene mass yield over time. Results indicate that the minimum mean particle diameter was observed to be 2 microns, which progressively grew up to 80 microns. The mean particle diameter exhibited a positive correlation with both asphaltene concentration and shear rate, whereas an inverse correlation was seen with heptane concentration. Furthermore, the asphaltene mass yield was found to increase with greater asphaltene and heptane concentrations, as well as with higher shear rates. The relationship between mean particle diameter and mass yield was found to be nonlinear. In the early stages, a higher prevalence of small particles contributed to a greater total particle count, while at later stages, particle aggregation led to the formation of larger particles that influenced the overall asphaltene mass. The insights gained from understanding the relationship between particle diameter, count, and mass yield are crucial for advancing the fundamental science of asphaltene precipitation and deposition. These findings may also guide future research that relies solely on particle counts for assessing asphaltene deposition.

Keywords

Asphaltene kinetics, aggregate kinetics, precipitation kinetics

Subject

Chemistry and Materials Science, Physical Chemistry

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