Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Deep Eutectic Solvents and Rare Earth Elements

Version 1 : Received: 5 February 2024 / Approved: 6 February 2024 / Online: 6 February 2024 (09:29:58 CET)

A peer-reviewed article of this Preprint also exists.

Alguacil, F.J. Utilizing Deep Eutectic Solvents in the Recycle, Recovery, Purification and Miscellaneous Uses of Rare Earth Elements. Molecules 2024, 29, 1356. Alguacil, F.J. Utilizing Deep Eutectic Solvents in the Recycle, Recovery, Purification and Miscellaneous Uses of Rare Earth Elements. Molecules 2024, 29, 1356.

Abstract

The boosted interest in the use of rare earth elements (REEs) in modern technologies had also increase the necessity of their recovery from various sources, including raw materials and wastes. Though Hydrometallurgy plays a key role in these recovery processes, some drawbacks (apparent or not) of these processes, had led to the development of a more environmental friendship subclass named Solvometallurgy, in which non-aqueous solvents substituted to the aqueous media of the hydrometallurgical processing. The non-aqueous solvents chosen for these usages are, besides ionic liquids (ILs), the so-named Deep Eutectic Solvents (DEEs). The utilization of DEEs included the leaching of REEs from the different sources containing them, and also in the separation-purification steps necessary for the yielding of these elements, normally as oxides or salts, in the most purified form. This work reviewed the most recent literature (2023 year) about the utilization of deep eutectic solvents in the recovery of REEs from various sources, and in the coupling of these two (DESs and REEs) to derived compounds to be used in other fields.

Keywords

deep eutectic solvents; rare earth elements; leaching; separation; purification     

Subject

Chemistry and Materials Science, Metals, Alloys and Metallurgy

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