Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Formal Assessment of Agreement and Similarity between an Open-Source and a Reference Industrial Device, with an Application to a Low-Cost pH Logger

Version 1 : Received: 16 December 2023 / Approved: 18 December 2023 / Online: 19 December 2023 (09:38:42 CET)

A peer-reviewed article of this Preprint also exists.

Bataka, E.P.; Maletsika, P.; Nakas, C.T. Formal Assessment of Agreement and Similarity between an Open-Source and a Reference Industrial Device with an Application to a Low-Cost pH Logger. Sensors 2024, 24, 490. Bataka, E.P.; Maletsika, P.; Nakas, C.T. Formal Assessment of Agreement and Similarity between an Open-Source and a Reference Industrial Device with an Application to a Low-Cost pH Logger. Sensors 2024, 24, 490.

Abstract

Open-source devices are nowadays used in a vast number of research fields like medicine, education, agriculture, and sports among others. In this work, an open-source, portable, low cost pH logger, appropriate for in situ meas-urements was designed and developed to assist in experiments on agricultural produce manufacturing. Τhe device was calibrated manually using pH buffers for values of 4.01 and 7.01. Then it was tested by manually measuring pH from the juice of citrus fruits. A waterproof temperature sensor was added to the device for temperature compen-sation when measuring pH. A formal method comparison process between the open-source device and a Hanna HI9024 Waterproof pH Meter was designed to assess their agreement. We derived indices of agreement and graph-ical assessment tools using mixed-effects models. Advantages and disadvantages for interpreting agreement through the proposed procedure are discussed. In our illustration, indices reported mediocre agreement and the subsequent similarity analysis revealed a fixed bias of 0.22 pH units. After recalibration, agreement between the devices im-proved to excellent levels. The process can be followed in general to avoid misleading or over-simplistic results of studies reporting solely correlation coefficients for formal comparison purposes.

Keywords

open-source logger; open-source software; agreement; similarity; pH

Subject

Biology and Life Sciences, Agricultural Science and Agronomy

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