Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Development of a More Sustainable Hybrid Process for Lithium and Cobalt Recovering From Lithium-Ion Batteries

Version 1 : Received: 30 April 2023 / Approved: 1 May 2023 / Online: 1 May 2023 (03:41:58 CEST)

A peer-reviewed article of this Preprint also exists.

Model, J.C.M.; Veit, H.M. Development of a More Sustainable Hybrid Process for Lithium and Cobalt Recovery from Lithium-Ion Batteries. Minerals 2023, 13, 798. Model, J.C.M.; Veit, H.M. Development of a More Sustainable Hybrid Process for Lithium and Cobalt Recovery from Lithium-Ion Batteries. Minerals 2023, 13, 798.

Abstract

The lithium-ion batteries are widely used as a power source for portable devices, including cell phones. The useful life is about 2 years or 500 cycles, contributing to the generation of waste from electrical and electronic equipment (WEEE). Mining of lithium and cobalt damages the environment and is onerous; therefore, sustainable alternatives, such as obtaining these elements from secondary sources as recycling of lithium-ion batteries, are essential to provide the inputs used in the sector. However, the metallurgical route which will used to recovering them must be considered, due to this work aims for a more environmentally favorable process using DL-malic acid 1.5 M and instead of compared with sulfuric acid 2 M, heat pretreatment of 1 h and 3 h, and for all conditions, experiments were carried out with and without adding the oxidizing agent hydrogen peroxide. The best yields occurred in presence of H2O2 10 % v/v, and heat pretreatment of 1 h: 33.49 % Co and 4.63 % Li, and 29.78 % Co e 3.44 % Li were recovered by sulfuric acid and DL-malic acid, respectively.

Keywords

Recycling; DL-Malic Acid; WEEE; eco-friendly; pretreatment

Subject

Engineering, Metallurgy and Metallurgical Engineering

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