Preprint Case Report Version 1 Preserved in Portico This version is not peer-reviewed

Looking Deeper into the Galaxy (Note 7)

Version 1 : Received: 21 December 2017 / Approved: 21 December 2017 / Online: 21 December 2017 (17:32:42 CET)

A peer-reviewed article of this Preprint also exists.

Loveridge, M.J.; Remy, G.; Kourra, N.; Genieser, R.; Barai, A.; Lain, M.J.; Guo, Y.; Amor-Segan, M.; Williams, M.A.; Amietszajew, T.; Ellis, M.; Bhagat, R.; Greenwood, D. Looking Deeper into the Galaxy (Note 7). Batteries 2018, 4, 3. Loveridge, M.J.; Remy, G.; Kourra, N.; Genieser, R.; Barai, A.; Lain, M.J.; Guo, Y.; Amor-Segan, M.; Williams, M.A.; Amietszajew, T.; Ellis, M.; Bhagat, R.; Greenwood, D. Looking Deeper into the Galaxy (Note 7). Batteries 2018, 4, 3.

Abstract

Li-ion cell designs, component integrity and manufacturing processes all have critical influence on the safety of Li-ion batteries. Any internal defective features that induce a short circuit, can trigger a thermal runaway: a cascade of reactions, leading to a device fire. As consumer device manufacturers push aggressively for increased battery energy, instances of field failure are increasingly reported. Notably Samsung made a press release in 2017 following a total product recall of their Galaxy Note 7 mobile phone, confirming speculation that the events were attributable to the battery and its mode of manufacture. Recent incidences of battery swelling on the new iPhone 8 have been reported in the media, and the techniques and lessons reported herein may have future relevance. Here we look deeper into the key components of one of these cells and confirm evidence of cracking of electrode material in tightly folded areas, combined with a delamination of surface coating on the separator, which itself is an unusually thin monolayer. We report microstructural information about the electrodes, battery welding attributes and thermal mapping of the battery whilst operational. The findings point to the most likely combination of events and highlights the impact of design features, whilst providing structural considerations most likely to have led to the reported incidences relating to this phone.

Keywords

Samsung Note 7 Li-ion, Thermal runaway, Ceramic coating, battery, Tomographic image, Welding characterisation

Subject

Physical Sciences, Applied Physics

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