The degradation and detachment of the polyamide (PA) layer in thin-film composite (TFC) membranes due to chlorine based chemical cleaning and material difference of PA layer and substrate are two major bottlenecks of forward osmosis (FO) technology. In this study, a new type of FO membranes were prepared by controlling self-polymerization of dopamine (DA) in the aqueous phase and the reaction with trimesoyl chloride (TMC) during interfacial polymerization (IP) process. These membranes were characterized by attenuated total reflection Fourier transform infrared (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM) and water contact angle measurements. The influence of synthesis parameters such as pH of the aqueous phase, reaction time, temperature, and monomer concentrations were systematically investigated. The optimized membrane showed enhanced structure stability in ethanol (7.1 times higher) and chlorine resistance (72.3 times higher) than the conventional Piperazine(PIP)/TMC membrane due to（poly-dopamine）PDA bio-adhesion and polyester groups in the membrane structure. In general, DA/TMC membranes could be an effective strategy to fabricate high-performance FO membranes with excellent structural stability and chlorine resistance.

Dye/salt separation has gained increasing attention in recent years, prompting the quest for cost-effective and environmentally-friendly raw materials for synthesis high performance nanofiltration (NF) membrane for effective dye/salt separation. Herein, a high-performance loose structured NF membrane was fabricated by via a simple vacuum filtration method using a green nanomaterial, 2,2,6,6-tetramethylpiperidine-1-oxide radical (TEMPO)-oxidized cellulose nanofiber (TOCNF), by sequentially filtrating larger-size and finer-size TOCNFs on a microporous substrate, followed by cross-linked with trimesoyl chloride. The resultant TCM membrane possesses a separating layer composed entirely of pure TOCNF, eliminating the need for other polymer or nanomaterials additives. TCM membranes exhibits high performance and effective dye/salt selectivity. Scanning Electron Microscope (SEM) analysis shows that the TCM membrane with Fine-TOCNF layer has a tight layered structure. Further characterizations via Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) confirm the presence of functional groups and chemical bonds of the crosslinked membrane. Notably, the optimized TCM-5 membrane exhibits a rejection rate of over 99% for various dyes (Congo red, orange yellow) and 14.2% for NaCl, showcasing a potential candidate for efficient dye wastewater treatment.