Yu, C.; Zhou, D.; Yan, X.; Gao, F.; Zhang, L.; Zhang, S.; Li, X. Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers2017, 9, 531.
Yu, C.; Zhou, D.; Yan, X.; Gao, F.; Zhang, L.; Zhang, S.; Li, X. Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers 2017, 9, 531.
Yu, C.; Zhou, D.; Yan, X.; Gao, F.; Zhang, L.; Zhang, S.; Li, X. Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers2017, 9, 531.
Yu, C.; Zhou, D.; Yan, X.; Gao, F.; Zhang, L.; Zhang, S.; Li, X. Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers 2017, 9, 531.
Abstract
A series of novel chiral nonmetallocene pincer-type rare earth metal dialkyl complexes bearing the chiral monoanionic tridentate C2-symmetric 1,3-bis(oxazolinymethylidene)isoindoline (BOXMI) ligand (BOXMI)Ln(CH2SiMe3)2 1-3 (1, Ln = Sc, yield = 57%; 2, Ln = Lu, yield = 55%; 3, Ln = Y, yield = 62%) have been prepared in moderate yields via the acid-base reaction between the BOXMI ligand and rare earth metal tri(trimethylsilylmethyl) complexes. The X-ray diffractions show that both of the complexes 1 and 2 contain one Boxmi ligand and two trimethylsilylmethyl ligands, adopting a distorted-trigonal-bipyramidal configuration. In the presence of cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities up to 6.8 × 104 (g of polymer)/(molLn h) and high cis-1,4-selectivities up to 97%) in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with high molecular weights (Mn up to 710000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5).
Keywords
rare earth metal complexes; 1,3-bis(oxazolinymethylidene)isoindoline ligand; polymerization; isoprene; cis-1,4-selectivity
Subject
Chemistry and Materials Science, Organic Chemistry
Copyright:
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