Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts2023, 13, 993.
Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts 2023, 13, 993.
Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts2023, 13, 993.
Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts 2023, 13, 993.
Abstract
A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO2 photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca2+ ions react with PO43- ions forming the HA particles. The photocatalytic formation of hydroxyapatite is found to have a fractional order, which may indicate the complex reaction mechanism and the presence of several limiting stages. The TNT-HA samples were studied by XRD, FTIR, SEM, GDOES, and biocompatibility study. High biocompatibility of the surfaces is proven by pre-osteoblast cell growth.
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